Iron(III) chloride in oxidative C-C coupling reactions

被引：416
作者：
Sarhan, Abdelwareth A. O. [1 ]
Bolm, Carsten [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany
来源：
CHEMICAL SOCIETY REVIEWS | 2009年 / 38卷 / 09期
关键词：
HEXA-PERI-HEXABENZOCORONENE; POLYCYCLIC AROMATIC-HYDROCARBONS; RAY CRYSTAL-STRUCTURE; INTRAMOLECULAR SCHOLL REACTION; SUBSTITUTED TRIPHENYLENES; ORGANIC-SYNTHESIS; SOLID-STATE; CHEMICAL POLYMERIZATION; ELECTRONIC-PROPERTIES; CATALYTIC-SYSTEM;
D O I：
10.1039/b906026j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this critical review, the use of iron(III) chloride in oxidative C-C couplings of arenes and related unsaturated compounds is presented and reviewed. The approach allows highly selective dimerisations of phenol derivatives, naphthols, and heterocyclic compounds. Sequential couplings give access to structurally well-defined oligo-and polymers. Iron(III) chloride is commercially available and inexpensive. Being a mild oxidising agent it has been applied in numerous reactions leading to new carbon -carbon-bonds in complex molecular arrays (107 references).
引用
收藏
页码：2730 / 2744
页数：15
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