One-dimensional structure of a photochromic coordination polymer composed of 1,2-bis[2-methyl-5-(4-pyridyl)-3-thienyl] cyclopentene and Zn(II) chloride

被引:17
作者
Qin, B [1 ]
Yao, RX [1 ]
Tian, H [1 ]
机构
[1] E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China
关键词
crystal structure; diarylethenes; photochromic; one-dimensional complex;
D O I
10.1016/j.ica.2004.03.028
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The crystal structure of the coordination polymer composed of 1,2-bis[2-methyl-5-(4-pyridyl)-3-thienyl]cyclopentene and Zn(II) chloride has been determined at 293 K. The photochromic ligand coordinates to the Zn cations adopting a C-2 symmetry geometry. The distance between the central reaction carbons is short enough to undergo photochromic reaction. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:3382 / 3384
页数:3
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