[3+2] Cycloaddition of aza-oxyallyl cations with aldehydes

被引：52

作者：

Jia, Qianfa ^{[1
]}

Du, Zhiyun ^{[1
]}

Zhang, Kun ^{[1
]}

Wang, Jian ^{[2
]}

机构：

[1] Guangdong Univ Technol, Allan H Conney Lab Anticancer Research, Guangzhou 510006, Guangdong, Peoples R China

[2] Tsinghua Univ, Sch Pharmaceut Sci, Beijing 100084, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2017年 / 4卷 / 01期

基金：

中国国家自然科学基金;

关键词：

AZAOXYALLYL CATIONS; AZOMETHINE IMINES; ACCESS; 4-OXAZOLIDINONES; PYRROLOINDOLINES; OXAZIRIDINES; INHIBITOR;

D O I：

10.1039/c6qo00526h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report here the [3 + 2] cycloaddition reactions of in situ-generated aza-oxyallyl cations with commercially available a, a-unsaturated aldehydes or aldehydes, providing a rapid and efficient synthetic approach to access a variety of oxazolidin-4-ones in high yields.

引用

页码：91 / 94

页数：4

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