Hydroxyapatite Wrapped Multiwalled Carbon Nanotubes/Ionic Liquid Composite Electrode: A High Performance Sensor for Trace Determination of Lead Ions

被引：12
|
作者：
Safavi, Afsaneh [1 ,2 ]
Sorouri, Mohsen [1 ]
Khanipour, Peyman [1 ]
机构：
[1] Shiraz Univ, Dept Chem, Coll Sci, Shiraz 71454, Iran
[2] Shiraz Univ, Nanotechnol Res Inst, Shiraz 71454, Iran
来源：
ELECTROANALYSIS | 2014年 / 26卷 / 02期
关键词：
Carbon nanotubes; Hydroxyapatite; Ionic liquids; Lead; Stripping analysis; ANODIC-STRIPPING VOLTAMMETRY; HEAVY-METALS; GENERATION; CADMIUM; CD2+;
D O I：
10.1002/elan.201300325
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A nanocomposite consisting of multiwalled carbon nanotubes wrapped with hydroxyapatite (HA/MWCNTs) was used in the construction of a new composite paste electrode using an ionic liquid as the binder. The stable surface in aqueous solutions as well as the high sorptive behaviors towards heavy metal ions and the favorable charge transfer make the electrode highly efficient especially for stripping or adsorptive analysis. The analysis of Pb2+ as a model of heavy metal ions has been performed. Good sensitivity, detection limit, selectivity and reproducibility were obtained for the suggested sensor. The linear range of the electrode response covered four orders of magnitude (1nM-10 mu M), in two linear ranges. The obtained detection limit for Pb2+ was 2x10(-11)M.
引用
收藏
页码：359 / 365
页数：7
相关论文
共 50 条
  • [21] Square wave anodic stripping voltammetric determination of lead(II) using a glassy carbon electrode modified with a lead ionophore and multiwalled carbon nanotubes
    He, Xiuhui
    Chen, Li
    Xie, Xuan
    Su, Zhaohong
    Qin, Cong
    Liu, Ying
    Ma, Ming
    Yao, Shouzhuo
    Deng, Le
    Xie, Qingji
    Tian, Yun
    Qin, Dilan
    Luo, Yueping
    MICROCHIMICA ACTA, 2012, 176 (1-2) : 81 - 89
  • [22] Electrochemical behavior of hydroquinone at multi-walled carbon nanotubes and ionic liquid composite film modified electrode
    Liu, Xiuhui
    Ding, Zhen
    He, Yuehua
    Xue, Zhonghua
    Zhao, Xueping
    Lu, Xiaoquan
    COLLOIDS AND SURFACES B-BIOINTERFACES, 2010, 79 (01) : 27 - 32
  • [23] Synthesis and characterization of cellulose and hydroxyapatite-carbon electrode composite for trace plumbum ions detection and its validation in blood serum
    Ajab, Huma
    Dennis, John Ojur
    Abdullah, Mohd Azmuddin
    INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2018, 113 : 376 - 385
  • [24] Cellulose-hydroxyapatite carbon electrode composite for trace plumbum ions detection in aqueous and palm oil mill effluent: Interference, optimization and validation studies
    Ajab, Huma
    Khan, Aamir Amanat Ali
    Nazir, Muhammad Shahid
    Yaqub, Asim
    Abdullah, Mohd Azmuddin
    ENVIRONMENTAL RESEARCH, 2019, 176
  • [25] Ionic liquid/multiwall carbon nanotubes paste electrode for square wave voltammetric determination of methyldopa
    Fouladgar, Masoud
    Karimi-Maleh, Hassan
    IONICS, 2013, 19 (08) : 1163 - 1170
  • [26] Ionic liquid/multiwall carbon nanotubes paste electrode for square wave voltammetric determination of methyldopa
    Masoud Fouladgar
    Hassan Karimi-Maleh
    Ionics, 2013, 19 : 1163 - 1170
  • [27] Electrochemical sensor based on EDTA functionalized carbon nanotubes for anodic stripping determination of lead ions
    Ma, Jingying
    Hong, Xiaoping
    DESALINATION AND WATER TREATMENT, 2022, 252 : 140 - 147
  • [28] Differential Pulse Anodic Stripping Voltammetry Determination of Lead(II) and Cadmium(II) with Multiwalled Carbon Nanotubes-Thiol Functionalized Chitosan Modified Bismuth Film Electrode
    Guo, Yan
    Ma, Yan
    Gao, Guizhi
    Li, Jun
    Xu, Jianqiang
    ASIAN JOURNAL OF CHEMISTRY, 2014, 26 (01) : 113 - 118
  • [29] Green sample clean-up based on magnetic multiwalled carbon nanotubes for the determination of lamivudine by high performance liquid chromatography
    Wang, Lingling
    Xu, Xu
    Zhang, Zhenzhen
    Zhang, Danfeng
    Liu, Xueyan
    Zhang, Lei
    RSC ADVANCES, 2015, 5 (28): : 22022 - 22030
  • [30] Trace level voltammetric determination of lead and cadmium in sediment pore water by a bismuth-oxychloride particle-multiwalled carbon nanotube composite modified glassy carbon electrode
    Cerovac, Sandra
    Guzsvany, Valeria
    Konya, Zoltan
    Ashrafi, Amir M.
    Svancara, Ivan
    Roncevic, Srdan
    Kukovecz, Akos
    Dalmacija, Bozo
    Vytras, Karel
    TALANTA, 2015, 134 : 640 - 649
12345