Metal-catalyzed hydrolysis of ammonia borane: Mechanism, catalysts, and challenges

被引：102

作者：

Wu, Han ^{[1
]}

Cheng, Yaojia ^{[2
]}

Fan, Yanping ^{[3
]}

Lu, Xingmei ^{[2
]}

Li, Lixin ^{[1
]}

Liu, Baozhong ^{[1
,3
]}

Li, Baojun ^{[2
]}

Lu, Siyu ^{[2
]}

机构：

[1] Henan Polytech Univ, Sch Mat Sci & Engn, Jiaozuo 454000, Henan, Peoples R China

[2] Zhengzhou Univ, Coll Chem, Zhengzhou 450001, Henan, Peoples R China

[3] Henan Polytech Univ, Coll Chem & Chem Engn, Jiaozuo 454000, Henan, Peoples R China

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2020年 / 45卷 / 55期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

Ammonia borane; Metal-catalyzed hydrolysis; Hydrogen; Mechanism; HIGHLY-ACTIVE CATALYST; SUPPORTED RU NANOPARTICLES; NITROGEN-DOPED GRAPHENE; COST-EFFECTIVE CATALYST; HYDROGEN GENERATION; EFFICIENT CATALYSTS; NICKEL NANOPARTICLES; ORGANIC FRAMEWORKS; SODIUM-BOROHYDRIDE; COBALT(0) NANOCLUSTERS;

D O I：

10.1016/j.ijhydene.2020.08.131

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ammonia borane is a promising material for hydrogen storage. In particular, its metal-catalyzed hydrolysis, which can occur under mild conditions and release a high amount (7%-8%) of hydrogen, has attracted considerable recent attention. Most previous studies have sought to improve the hydrolysis rate, leading to a relatively asymmetric research trend, where some potential problems must be overcome before its industrialization. A comprehensive analysis and systematic overview of current research would therefore be helpful to future works. This review first discusses the hydrolysis of ammonia borane in detail. It then summarizes and analyzes recent development of metal catalysts. Some challenges related to the hydrolysis system are also discussed, and finally, some perspectives on emerging issues regarding the future development of this system are provided. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：30325 / 30340

页数：16

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