Synthesis and catalytic performance of Ti-MCM-68 for effective oxidation reactions

被引:73
作者
Kubota, Yoshihiro [1 ]
Koyama, Yoshihito [1 ]
Yamada, Taku [1 ]
Inagaki, Satoshi [1 ]
Tatsumi, Takashi [2 ]
机构
[1] Yokohama Natl Univ, Div Mat Sci & Chem Engn, Hodogaya Ku, Yokohama, Kanagawa 2408501, Japan
[2] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2258503, Japan
关键词
D O I
10.1039/b814286f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Microporous titanosilicate Ti-MCM-68 (Ti-MSE) was successfully synthesized by post-synthetic isomorphous substitution of Ti for Al and proved to be a high-performance catalyst, in particular showing superior performance to TS-1, Ti-BEA, and Ti-MWW for phenol oxidation using H(2)O(2) as an oxidant.
引用
收藏
页码:6224 / 6226
页数:3
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