Synthesis and catalytic performance of Ti-MCM-68 for effective oxidation reactions

被引：73

作者：

Kubota, Yoshihiro ^{[1
]}

Koyama, Yoshihito ^{[1
]}

Yamada, Taku ^{[1
]}

Inagaki, Satoshi ^{[1
]}

Tatsumi, Takashi ^{[2
]}

机构：

[1] Yokohama Natl Univ, Div Mat Sci & Chem Engn, Hodogaya Ku, Yokohama, Kanagawa 2408501, Japan

[2] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2258503, Japan

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 46期

关键词：

D O I：

10.1039/b814286f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Microporous titanosilicate Ti-MCM-68 (Ti-MSE) was successfully synthesized by post-synthetic isomorphous substitution of Ti for Al and proved to be a high-performance catalyst, in particular showing superior performance to TS-1, Ti-BEA, and Ti-MWW for phenol oxidation using H(2)O(2) as an oxidant.

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收藏

页码：6224 / 6226

页数：3

相关论文

共 29 条

[1] Activities and stabilities of heterogeneous catalysts in selective liquid phase oxidations: recent developments [J].

Arends, IWCE ;

Sheldon, RA .

APPLIED CATALYSIS A-GENERAL, 2001, 212 (1-2) :175-187

[2]

Baerlocher C, 2007, ATLAS ZEOLITE FRAMEW

[3]

Calabro D. C., 2000, US Pat., Patent No. [6049018, 6,049018]

[4] SYNTHESIS OF A TITANIUMSILICOALUMINATE ISOMORPHOUS TO ZEOLITE-BETA AND ITS APPLICATION AS A CATALYST FOR THE SELECTIVE OXIDATION OF LARGE ORGANIC-MOLECULES [J].

CAMBLOR, MA ;

CORMA, A ;

MARTINEZ, A ;

PEREZPARIENTE, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (08) :589-590

[5] Characterization and catalytic activity of titanium containing SSZ-33 and aluminum-free zeolite beta [J].

Dartt, CB ;

Davis, ME .

APPLIED CATALYSIS A-GENERAL, 1996, 143 (01) :53-73

[6] Synthesis and catalytic activity of Ti-ITQ-7:: a new oxidation catalyst with a three-dimensional system of large pore channels [J].

Díaz-Cabaña, MJ ;

Villaescusa, LA ;

Camblor, MA .

CHEMICAL COMMUNICATIONS, 2000, (09) :761-762

[7] Crystal structure of zeolite MCM-68: A new three-dimensional framework with large pores [J].

Dorset, DL ;

Weston, SC ;

Dhingra, SS .

JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (05) :2045-2050

[8] A comparative study of zeolites SSZ-33 and MCM-68 for hydrocarbon trap applications [J].

Elangovan, S. P. ;

Ogura, Masaru ;

Ernst, Stefan ;

Hartmann, Martin ;

Tontisirin, Supak ;

Davis, Mark E. ;

Okubo, Tatsuya .

MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 96 (1-3) :210-215

[9]

ERNST S, 14 INT ZEOL C 2004, P982

[10] A multi-dimensional microporous silicate that is isomorphous to zeolite MCM-68 [J].

Koyama, Yoshihito ;

Ikeda, Takuji ;

Tatsumi, Takashi ;

Kubota, Yoshihiro .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (06) :1042-1046