Structure and magnetism of copper-substituted cobalt ludwigite Co3O2BO3

被引:13
作者
Ivanova, N. B. [1 ,2 ]
Kazak, N. V. [2 ]
Knyazev, Yu V. [1 ]
Velikanov, D. A. [1 ,2 ]
Vasiliev, A. D. [1 ,2 ]
Bezmaternykh, L. N. [2 ]
Platunov, M. S. [2 ]
机构
[1] Siberian Fed Univ, Krasnoyarsk 660074, Russia
[2] Russian Acad Sci, Siberian Branch, LV Kirensky Inst Phys, Krasnoyarsk 660036, Russia
基金
俄罗斯基础研究基金会;
关键词
CRYSTAL-STRUCTURE;
D O I
10.1063/1.4818633
中图分类号
O59 [应用物理学];
学科分类号
摘要
Single crystals of Co3O2BO3 with partial (4%) substitution of Co by Cu ions were synthesized by the flux technique. X-ray diffraction and magnetic studies were carried out. The x-ray diffraction measurements show clearly that Cu preferentially occupies only one of the four nonequivalent crystallographic positions, the one with the smallest electric field gradient. The ferrimagnetic ordering near T-N=43K and the high magnetic hardness in this magnetic phase are similar to those of Co3O2BO3. Copper substitution causes a small reduction in the effective magnetic moment. (C) 2013 AIP Publishing LLC.
引用
收藏
页码:709 / 713
页数:5
相关论文
共 15 条
  • [1] Uniaxial magnetic anisotropy in Co2.25Fe0.75O2BO3 compared to Co3O2BO3 and Fe3O2BO ludwigites
    Bartolome, J.
    Arauzo, A.
    Kazak, N. V.
    Ivanova, N. B.
    Ovchinnikov, S. G.
    Knyazev, Yu. V.
    Lyubutin, I. S.
    [J]. PHYSICAL REVIEW B, 2011, 83 (14)
  • [2] THE PROGNOSTICATION POSSIBILITY OF SOME MAGNETIC-PROPERTIES FOR DIELECTRICS ON THE BASIS OF COVALENCY PARAMETERS OF LIGAND CATION BONDS
    BAYUKOV, OA
    SAVITSKII, AF
    [J]. PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1989, 155 (01): : 249 - 255
  • [3] Magnetic structure and charge ordering in Fe3BO5: A single-crystal x-ray and neutron powder diffraction study
    Bordet, P.
    Suard, E.
    [J]. PHYSICAL REVIEW B, 2009, 79 (14)
  • [4] Structural and magnetic properties of the oxyborate Co5Ti(O2BO3)2
    Freitas, D. C.
    Guimaraes, R. B.
    Sanchez, D. R.
    Fernandes, J. C.
    Continentino, M. A.
    Ellena, J.
    Kitada, A.
    Kageyama, H.
    Matsuo, A.
    Kindo, K.
    Eslava, G. G.
    Ghivelder, L.
    [J]. PHYSICAL REVIEW B, 2010, 81 (02)
  • [5] Partial magnetic ordering and crystal structure of the ludwigites Co2FeO2BO3 and Ni2FeO2BO3
    Freitas, D. C.
    Continentino, M. A.
    Guimaraes, R. B.
    Fernandes, J. C.
    Oliveira, E. P.
    Santelli, R. E.
    Ellena, J.
    Eslava, G. G.
    Ghivelder, L.
    [J]. PHYSICAL REVIEW B, 2009, 79 (13)
  • [6] Spin-glass magnetic ordering in CoMgGaO2BO3 ludwigite
    Ivanova, N. B.
    Platunov, M. S.
    Knyazev, Yu. V.
    Kazak, N. V.
    Bezmaternykh, L. N.
    Eremin, E. V.
    Vasiliev, A. D.
    [J]. LOW TEMPERATURE PHYSICS, 2012, 38 (02) : 172 - 174
  • [7] Specific heat study of SrCu2(BO3)2
    Kageyama, H
    Suzuki, H
    Nohara, M
    Onizuka, K
    Takagi, H
    Ueda, Y
    [J]. PHYSICA B, 2000, 281 (281): : 667 - 668
  • [8] Synthesis, crystal structure and characterization of iron pyroborate (Fe2B2O5) single crystals
    Kawano, Tetsuya
    Morito, Haruhiko
    Yamada, Takahiro
    Onuma, Takeyoshi
    Chichibu, Shigefusa F.
    Yamane, Hisanori
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2009, 182 (08) : 2004 - 2009
  • [9] The superexchange interactions in mixed Co-Fe ludwigite
    Kazak, N. V.
    Ivanova, N. B.
    Bayukov, O. A.
    Ovchinnikov, S. G.
    Vasiliev, A. D.
    Rudenko, V. V.
    Bartolome, J.
    Arauzo, A.
    Knyazev, Yu V.
    [J]. JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2011, 323 (05) : 521 - 527
  • [10] Conductivity study of Co3O2BO3 and Co3-xFexO2BO3 oxyborates
    Kazak, N. V.
    Ivanova, N. B.
    Rudenko, V. V.
    Ovchinnikov, S. G.
    Vasil'ev, A. D.
    Knyazev, Yu. V.
    [J]. MAGNETISM AND MAGNETIC MATERIALS, 2009, 152-153 : 104 - +