Evaluation of carbohydrates and lignocellulosic biomass from different wood species as raw material for the synthesis of 5-bromomethyfurfural

被引:31
作者
Bredihhin, Aleksei [1 ]
Maeeorg, Uno [2 ]
Vares, Lauri [1 ]
机构
[1] Univ Tartu, Inst Technol, EE-50411 Tartu, Estonia
[2] Univ Tartu, Inst Chem, EE-50411 Tartu, Estonia
关键词
Biomass; Biofuels; Cellulose; 5-Ethoxymethylfurfural; 5-Bromomethylfurfural; ETHERIFICATION; CONVERSION; CELLULOSE;
D O I
10.1016/j.carres.2013.04.002
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The influence of different parameters on the conversion of carbohydrates and biomass into the potential biofuel intermediate 5-bromomethylfurfural (BMF) has been studied. Our optimized conditions avoid the use of lithium salt additives, making this method cheaper and environmentally more benign compared to previously reported methods. Different wood species and their potential as a raw material in BMF and furfural production have also been evaluated. In addition, we report a very simple and efficient procedure for conversion of 5-hydroxymethylfurfural (HMF) into BMF or 5-chloromethylfurfural (CMF). (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:63 / 67
页数:5
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