Triphenylene-based tris-N-heterocyclic stannylenes

被引:5
|
作者
Hsu, Chen-Yuan [1 ]
Chan, Li-Wei [1 ]
Lee, Gene-Hsiang [1 ]
Peng, Shie-Ming [1 ]
Chiu, Ching-Wen [1 ]
机构
[1] Natl Taiwan Univ, Dept Chem, Taipei 10617, Taiwan
关键词
CARBENE HOMOLOGS; TIN ANALOGS; GERMYLENES; CHEMISTRY; SN; BISSTANNYLENES; COMPLEXES; GERMANIUM; ELEMENT; AMIDES;
D O I
10.1039/c5dt00694e
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two planar tridentate N-heterocyclic stannylenes are synthesized from the corresponding 2,3,6,7,10,11-hexaamino-triphenylene and Sn[N(TMS)(2)](2). Multinuclear NMR and absorption spectra of these tris-stannylenes are reported. Molecular structure of the N-benzhydryl-substituted tris-stannylene is also realized.
引用
收藏
页码:15095 / 15098
页数:4
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