Triphenylene-based tris-N-heterocyclic stannylenes

被引：5
作者：
Hsu, Chen-Yuan [1 ]
Chan, Li-Wei [1 ]
Lee, Gene-Hsiang [1 ]
Peng, Shie-Ming [1 ]
Chiu, Ching-Wen [1 ]
机构：
[1] Natl Taiwan Univ, Dept Chem, Taipei 10617, Taiwan
来源：
DALTON TRANSACTIONS | 2015年 / 44卷 / 34期
关键词：
CARBENE HOMOLOGS; TIN ANALOGS; GERMYLENES; CHEMISTRY; SN; BISSTANNYLENES; COMPLEXES; GERMANIUM; ELEMENT; AMIDES;
D O I：
10.1039/c5dt00694e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two planar tridentate N-heterocyclic stannylenes are synthesized from the corresponding 2,3,6,7,10,11-hexaamino-triphenylene and Sn[N(TMS)(2)](2). Multinuclear NMR and absorption spectra of these tris-stannylenes are reported. Molecular structure of the N-benzhydryl-substituted tris-stannylene is also realized.
引用
收藏
页码：15095 / 15098
页数：4
相关论文
共 48 条
  • [1] Attachment of the new bulky ligand (Me3Si)2(Me2NMe2Si)C to Li, Hg, Al, Ga, and Sn.: Crystal structures of [Li{C(SiMe3)2(SiMe2NMe2)}(THF)2], [Hg{C(SiMe3)2(SiMe2NMe2)}2], [Al{C(SiMe3)2(SiMe2NMe2)}X2] (X = Cl, Ph), and [Ga{C(SiMe3)2(SiMe2NMe2)}Cl2]
    Al-Juaid, SS
    Eaborn, C
    El-Hamruni, SM
    Hitchcock, PB
    Smith, JD
    [J]. ORGANOMETALLICS, 1999, 18 (01) : 45 - 52
  • [2] N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands
    Asay, Matthew
    Jones, Cameron
    Driess, Matthias
    [J]. CHEMICAL REVIEWS, 2011, 111 (02) : 354 - 396
  • [3] SYNTHESIS AND CHARACTERIZATION OF N,N'-DISUBSTITUTED 1,2-PHENYLENEBIS(AMIDO)TIN(II) COMPOUNDS - X-RAY STRUCTURES OF 1,2-C6H4[N(CH(2)BU(T))]SN-2 AND OF [1,2-C6H4(N(SIME(3)))SN-2](2)(TMEDA)
    BRAUNSCHWEIG, H
    GEHRHUS, B
    HITCHCOCK, PB
    LAPPERT, MF
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (11): : 1922 - 1928
  • [4] Noncovalently Netted, Photoconductive Sheets with Extremely High Carrier Mobility and Conduction Anisotropy from Triphenylene-Fused Metal Trigon Conjugates
    Chen, Long
    Kim, Jangbae
    Ishizuka, Tomoya
    Honsho, Yoshihito
    Saeki, Akinori
    Seki, Shu
    Ihee, Hyotcherl
    Jiang, Donglin
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (21) : 7287 - 7292
  • [5] SUB-VALENT GROUP 4B METAL ALKYLS AND AMIDES .1. SYNTHESIS AND PHYSICAL-PROPERTIES OF KINETICALLY STABLE BIS[BIS(TRIMETHYSILYL)METHYL]-GERMANIUM(II), BIS[BIS(TRIMETHYSILYL)METHYL]-TIN(II), AND BIS[BIS(TRIMETHSILYL)METHYL]-LEAD(II)
    DAVIDSON, PJ
    HARRIS, DH
    LAPPERT, MF
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (21): : 2268 - 2274
  • [6] Sterically demanding and chiral N,N′-disubstituted N-heterocyclic germylenes and stannylenes
    Dickschat, Julia V.
    Urban, Slawomir
    Pape, Tania
    Glorius, Frank
    Hahn, F. Ekkehardt
    [J]. DALTON TRANSACTIONS, 2010, 39 (48) : 11519 - 11521
  • [7] Characterization of the sterically encumbered terphenyl-substituted species 2,6-Trip2H3C6Sn-Sn(Me)2C6H3-2,6-Trip2, an unsymmetric, group 14 element, methylmethylene, valence isomer of an alkene, its related lithium derivative 2,6-Trip2H3C6(Me)2Sn-Sn(Li)(Me)C6H3-2,6-Trip2, and the monomer Sn(t-Bu)C6H3-2,6-Trip2 (Trip = C6H2-2,4,6-i-Pr3)
    Eichler, BE
    Power, PP
    [J]. INORGANIC CHEMISTRY, 2000, 39 (24) : 5444 - 5449
  • [8] The transfer of tin and germanium atoms form N-heterocyclic stannylenes and germylenes to diazadienes
    Gans-Eichler, T
    Gudat, D
    Nättinen, K
    Nieger, M
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (04) : 1162 - 1173
  • [9] Gans-Eichler T, 2002, ANGEW CHEM INT EDIT, V41, P1888, DOI 10.1002/1521-3773(20020603)41:11<1888::AID-ANIE1888>3.0.CO
  • [10] 2-O
12345