Synthesis and Crystal Structure of Chiral Substituted (S)-2-[(4-Methoxyphenoxy) Methyl]-15-Crown-5 Ether with Sodium Perchlorate Complex

被引：3
|
作者：
Dogan, Nermin [1 ]
Ozbey, Sueheyla [1 ]
Karakaplan, Mehmet [2 ]
Aral, Tarik [2 ]
机构：
[1] Hacettepe Univ, Fac Engn, Dept Engn Phys, TR-06800 Ankara, Turkey
[2] Dicle Univ, Fac Arts & Sci, Dept Chem, TR-21280 Diyarbakir, Turkey
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2008年 / 38卷 / 12期
关键词：
Chiral crown ether; Sodium complex; 15-Crown-5; Crystal structure;
D O I：
10.1007/s10870-008-9417-8
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal and molecular structure of chiral crown ether, (S)-2-[(4-methoxyphenoxy)methyl]-15-crown-5 center dot NaClO4, has been determined by single-crystal X-ray diffraction. The complex crystallizes in the orthorombic space group Pbca with Z = 8. Lattice parameters are a = 11.451(2), b = 12.842(3), c = 31.330(7) angstrom. The structure was refined to R factor of 0.0547. The Na ion is heptacoordinated. The Na-O-ether distances range from 2.363(4) to 2.433(4) degrees and average 2.404(5) degrees. Perchlorate anion is bounded to sodium ion asymmetrically; the Na-O8 and Na-O9 distances are 2.444(5) degrees and 2.607(5) degrees. The C-O and C-C distances of the 15-membered ring average 1.419(9) and 1.478(12) degrees while the O-C-C and C-O-C angles average 108.2(6)degrees and 115.4(6)degrees.
引用
收藏
页码：943 / 947
页数：5
相关论文
共 50 条
  • [31] Synthesis, Characterization and Crystal Structure of (S)-2-(2-Hydroxynaphthalen-6-yl)-N-((pyridin-4-yl)methyl) Propanamide
    Wang, Shi
    He, Wenrui
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2011, 41 (06) : 783 - 786
  • [32] Synthesis, Characterization and Crystal Structure of (S)-2-(2-Hydroxynaphthalen-6-yl)-N-((pyridin-4-yl)methyl) Propanamide
    Shi Wang
    Wenrui He
    Journal of Chemical Crystallography, 2011, 41 : 783 - 786
  • [33] Synthesis, Crystal Structure, and Kinetics of the Thermal Decomposition of the Nickel(II) Complex of the Schiff Base 2-[(4-Methylphenylimino)methyl]-6-methoxyphenol
    Wang, Yan-Fang
    Liu, Jian-Feng
    Xian, Hui-Duo
    Zhao, Guo-Liang
    MOLECULES, 2009, 14 (07) : 2582 - 2593
  • [34] Synthesis, Crystal Structure and Herbicidal Activity of Methyl(E)-α-(Methoxyimino)-2-((4-(3-chloro-5-(trifluoromethyl)-pyridine-2-yl)phenoxy)methyl)benzeneacetate
    曹杨羊
    王维伟
    杜晓华
    ChineseJournalofStructuralChemistry, 2019, 38 (07) : 1123 - 1128
  • [35] Synthesis, Crystal Structure and Herbicidal Activity of Methyl (E)-α(Methoxyimino)-2-((4-(3-chloro-5-(trifluoromethyl)- pyridine-2-yl)phenoxy)methyl)benzeneacetate
    Cao Yang-Yang
    Wang Wei-Wei
    Du Xiao-Hua
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 38 (07) : 1123 - 1128
  • [36] Synthesis and Crystal Structure of a Compound with Two Conformational Isomers: 2-(2,6-Difluorobenzamido)-4-methyl-N-o-tolylthiazole-5-carboxamide
    Cai, Hua
    Guo, Ying
    Li, Jian-Gang
    Zou, Yun-Ling
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2010, 40 (02) : 100 - 103
  • [37] Synthesis and Crystal Structure of Nickel(II) Complex with 2-(3,5-Dibromo-2-hydroxyphenyl)-4-methyl-1,2-dihydroquinazoline-3-oxide
    Chai, Lan-Qin
    Zhang, Yu-Li
    Liu, Gang
    Huang, Jiao-Jiao
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (12) : 6780 - 6782
  • [38] Synthesis and Crystal Structure of a Compound with Two Conformational Isomers: 2-(2,6-Difluorobenzamido)-4-methyl-N–o-tolylthiazole-5-carboxamide
    Hua Cai
    Ying Guo
    Jian-Gang Li
    Yun-Ling Zou
    Journal of Chemical Crystallography, 2010, 40 : 100 - 103
  • [39] A New Mo(VI) Complex of (E)-2-(((5-hydroxypentyl)imino)methyl)-6-methoxyphenol: Synthesis, Characterization, and X-Ray Crystal Structure
    Sheikhshoaie, Iran
    Ebrahimipour, S. Yousef
    Shamsi, Somayeh
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2016, 46 (06) : 917 - 921
  • [40] Synthesis, Crystal Structure, and Computational Investigations of 2-(2-(4-Fluorophenyl)-2-oxoethyl)-6-methyl-5-(4-methylbenzyl)pyridazin-3(2H)-one as Antiviral Agent
    El Kalai, Fouad
    Abraham, Christina Susan
    Kansiz, Sevgi
    Oulmidi, Afaf
    Muthu, Sambantham
    Prasana, Johanan Christian
    Dege, Necmi
    Abuelizz, Hatem A. A.
    Al-Salahi, Rashad
    Benchat, Noureddine
    Karrouchi, Khalid
    CRYSTALS, 2023, 13 (07)
12345