Stability and solubility relationships in AFm phases - Part 1. Chloride, sulfate and hydroxide

被引：225

作者：

Glasser, FP ^{[1
]}

Kindness, A ^{[1
]}

Stronach, SA ^{[1
]}

机构：

[1] Univ Aberdeen, Dept Chem, Old Aberdeen AB24 3UE, Scotland

来源：

CEMENT AND CONCRETE RESEARCH | 1999年 / 29卷 / 06期

关键词：

AF(m) phases; monosulfoaluminate; chloride; solubility; Friedel's salt;

D O I：

10.1016/S0008-8846(99)00055-1

中图分类号：

TU [建筑科学];

学科分类号：

0813 ;

摘要：

Portland cements contain an AFm phase whose anion content is initially dominated by OH- (hydroxy) and SO42- (sulfate); variants such as those based on C(2)ASH(8) may occur in blended cements. In service conditions AF(m) phases may exhibit anion exchange, principally with carbonate, chloride, and additional sulfate. The chemistry, stability, and crystal chemistry of AF(m) phases are reviewed briefly. New data are presented on the role of 3CaOAl(2)O(3)0.5CaCl(2)0.5CaSO(4)10H(2)O, which, it is proposed, should be named Kuzel's salt after its discoverer. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：861 / 866

页数：6

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