Kinetics of tert amyl ethyl ether liquid phase synthesis catalyzed by ion exchange resin

被引:0
|
作者
Bozga, G [1 ]
Motelica, A [1 ]
Dima, R [1 ]
Plesu, V [1 ]
机构
[1] Univ Politehn Bucuresti, Bucharest 011061, Romania
来源
REVISTA DE CHIMIE | 2005年 / 56卷 / 11期
关键词
tert-amyl ethyl ether; etherification; amylenes; FCCC5; fraction; kinetics;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The kinetics of the liquid-phase synthesis of tert-amyl ethyl ether by direct etherification with ethanol of the reactive amylenes contained in the FCC light gasoline (C5 fraction) was theoretically and experimentally investigated. The catalyst used was a commercial Amberlyst-35 acid ion-exchange resin having the original grain size distribution. Experimental data were obtained in a laboratory scale continuous fixed bed reactor and a simple kinetic model was proposed based on hypothesis accepted in other published studies.
引用
收藏
页码:1073 / 1077
页数:5
相关论文
共 50 条
  • [31] KINETICS OF THE LIQUID-PHASE SYNTHESIS AND HYDROLYSIS OF BUTYL LACTATE CATALYZED BY CATION-EXCHANGE RESIN
    DASSY, S
    WIAME, H
    THYRION, FC
    JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 1994, 59 (02) : 149 - 156
  • [32] Reevaluation of microkinetic approaches to the liquid phase synthesis of ethyl tert-butyl ether
    Schwarzer, S
    Kunz, U
    Hoffmann, U
    CHEMIE INGENIEUR TECHNIK, 1999, 71 (08) : 864 - 868
  • [33] Experimental study of the simultaneous synthesis of methyl tert-butyl ether and ethyl tert-butyl ether in liquid phase
    Gomez, C
    Cunill, F
    Iborra, M
    Izquierdo, F
    Tejero, J
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1997, 36 (11) : 4756 - 4762
  • [34] INFLUENCE OF WATER ON THE GAS-PHASE DECOMPOSITION OF METHYL TERT-BUTYL ETHER CATALYZED BY A MACROPOROUS ION-EXCHANGE RESIN
    TEJERO, J
    CUNILL, F
    MANZANO, S
    APPLIED CATALYSIS, 1988, 38 (02): : 327 - 340
  • [35] Design, optimization, and control of reactive distillation column for the synthesis of tert-amyl ethyl ether
    Lei, Zhao
    Yi, Chunhai
    Yang, Bolun
    CHEMICAL ENGINEERING RESEARCH & DESIGN, 2013, 91 (05): : 819 - 830
  • [36] KINETICS OF METHYL TERTIARY BUTYL ETHER LIQUID-PHASE SYNTHESIS CATALYZED BY ION-EXCHANGE RESIN .2. MACROPORE DIFFUSION OF METHANOL AS RATE-CONTROLLING STEP
    REHFINGER, A
    HOFFMANN, U
    CHEMICAL ENGINEERING SCIENCE, 1990, 45 (06) : 1619 - 1626
  • [37] Kinetics of synthesis of ethyl acetate over strong acid ion exchange resin catalyst
    School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China
    不详
    Huaxue Fanying Gongcheng Yu Gongyi, 2008, 4 (363-367):
  • [38] Kinetic behavior of amyl acetate synthesis catalyzed by acidic cation exchange resin
    Lee, MJ
    Wu, HT
    Kang, CH
    Lin, HM
    JOURNAL OF THE CHINESE INSTITUTE OF CHEMICAL ENGINEERS, 1999, 30 (02): : 117 - 122
  • [39] Mass transfer effects on kinetics of nonideal liquid phase ethyl tert-butyl ether formation
    Sundmacher, Kai
    Zhang, Rui-Sheng
    Hoffmann, Ulrich
    Chemical Engineering and Technology, 1995, 18 (04): : 269 - 277
  • [40] EQUILIBRIUM-CONSTANTS FOR ETHYL TERT-BUTYL ETHER LIQUID-PHASE SYNTHESIS
    VILA, M
    CUNILL, F
    IZQUIERDO, JF
    TEJERO, J
    IBORRA, M
    CHEMICAL ENGINEERING COMMUNICATIONS, 1993, 124 : 223 - 232