Identification of intermediates, acute toxicity removal, and kinetics investigation to the Ametryn treatment by direct photolysis (UV254), UV254/H2O2, Fenton, and photo-Fenton processes

被引:20
作者
de Oliveira, Dirce Martins [1 ]
Cavalcante, Rodrigo Pereira [2 ]
da Silva, Lucas de Melo [2 ]
Sans, Carme [3 ]
Esplugas, Santiago [3 ]
de Oliveira, Silvio Cesar [1 ]
Machulek Junior, Amilcar [1 ,2 ]
机构
[1] Univ Fed Mato Grosso do Sul, Fac Engn Architecture & Urbanism & Geog, CP 549, BR-79070900 Campo Grande, MS, Brazil
[2] Univ Fed Mato Grosso do Sul, Inst Chem, Av Senador Filinto Muller 1555,CP 549, BR-79074460 Campo Grande, MS, Brazil
[3] Univ Barcelona, Dept Chem Engn, C Marti i Franques 1, E-08028 Barcelona, Spain
关键词
Fenton; Herbicide; Kinetic constant; Acute ecotoxicity; Degradation mechanism; Hydroxyl radical; Biodegradability; Water treatment; ADVANCED OXIDATION PROCESSES; WASTE-WATER TREATMENT; DEGRADATION PATHWAYS; TRIAZINE PESTICIDES; HYDROGEN-PEROXIDE; TITANIUM-DIOXIDE; AQUEOUS-SOLUTION; CEREAL SAMPLES; SOLAR; UV;
D O I
10.1007/s11356-018-1342-6
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This paper reports the degradation of 10 mg L-1 Ametryn solution with different advanced oxidation processes and by ultraviolet (UV254) irradiation alone with the main objective of reducing acute toxicity and increase biodegradability. The investigated factors included Fe2+ and H2O2 concentrations. The effectiveness of the UV254 and UV254/H2O2 processes were investigated using a low-pressure mercury UV lamp (254 nm). Photo-Fenton process was explored using a blacklight blue lamp (BLB, lambda = 365 nm). The UV254 irradiation process achieved complete degradation of Ametryn solution after 60 min. The degradation time of Ametryn was greatly improved by the addition of H2O2. It is worth pointing out that a high rate of Ametryn removal was attained even at low concentrations of H2O2. The kinetic constant of the reaction between Ametryn and HOau for UV254/H2O2 was 3.53 x 10(8) L mol(-1) s(-1). The complete Ametryn degradation by the Fenton and photo-Fenton processes was observed following 10 min of reaction for various combinations of Fe2+ and H2O2 under investigation. Working with the highest concentration (150 mg L-1 H2O2 and 10 mg L-1 Fe2+), around 30 and 70% of TOC removal were reached within 120 min of treatment by Fenton and photo-Fenton processes, respectively. Although it did not obtain complete mineralization, the intermediates formed in the degradation processes were hydroxylated and did not promote acute toxicity of Vibrio fischeri. Furthermore, a substantial improvement of biodegradability was obtained for all studied processes.
引用
收藏
页码:4348 / 4366
页数:19
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