Application of 1-(3-bromo-3,3-difluoroprop-1-ynyl)benzenes in Diels-Alder reactions:: Synthesis of ortho-CF2Br-substituted biaryls

被引：7

作者：

Muzalevskiy, Vasilly M. ^{[1
]}

Nenajdenko, Valentine G. ^{[1
]}

Shastin, Aleksey V. ^{[2
]}

Balenkova, Elizabeth S. ^{[1
]}

Haufe, Guenter ^{[3
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia

[2] Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia

[3] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

SYNTHESIS-STUTTGART | 2008年 / 18期

关键词：

alkynes; biaryls; bicyclic compounds; Diels-Alder reaction; fluorine;

D O I：

10.1055/s-2008-1067221

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1-(3-Bromo-3,3-difluoroprop-1-ynyl)benzenes were found to be good dienophiles in Diels-Alder reactions. Based oil this key reaction a new pathway towards biaryls with an ortho-CF2Br group was elaborated.

引用

页码：2899 / 2904

页数：6

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