Raman spectroscopy of beaverite and plumbojarosite

被引：16

作者：

Frost, RL ^{[1
]}

Wills, RA ^{[1
]}

Martens, W ^{[1
]}

机构：

[1] Queensland Univ Technol, Sch Phys & Chem Sci, Inorgan Mat Res Program, Brisbane, Qld 4001, Australia

来源：

JOURNAL OF RAMAN SPECTROSCOPY | 2005年 / 36卷 / 12期

关键词：

alunite; jarosite; plumbojarosite; beaverite;

D O I：

10.1002/jrs.1414

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Raman spectroscopy has been used to characterise the compound of formula Pb(Fe3+, Cu2+)(3)(SO4)(2)(OH)(6), equivalent to synthetic beaverite, one of the jarosite subgroup minerals. The mineral is characterised by multiple OH stretching vibrations attributed to non-equivalent OH units in the structure. Multiple vibrations are observed for the SO42- stretching vibrations indicating the non-equivalence of the sulphate units in the structure. This multiplicity is also reflected in the nu(2) and nu(4) bending modes. The Raman spectrum of beaverite is significantly different from that of plumbojarosite, for which multiple bands are not observed. Copyright (c) 2005 John Wiley & Sons, Ltd.

引用

页码：1106 / 1112

页数：7

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