Syntheses and characterization of two palladium complexes of isonitrosoacetylacetoneimine

被引：0

作者：

Feng, YL ^{[1
]}

Liu, SX

机构：

[1] Fuzhou Univ, Cent Lab, Fuzhou 350002, Peoples R China

[2] Zhejiang Normal Univ, Inst Phys Chem, Dept Chem, Jinhua 321004, Peoples R China

来源：

ACTA CHIMICA SINICA | 2002年 / 60卷 / 05期

关键词：

synthesis; crystal structure; palladium complex; isonitrosoacetylacetoneimine;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two palladium complexes of isonitrosoacetylacetoneimine, Pd (o-BrC6H4-IAI)(2) (1) and Pd (C6H5CH2-IAI)(2) (2), were synthesized and characterized by IR and Raman spectra. Complex 1 crystallizes in monoclinic system, space group P2(1)/c, with parameters: a = 0.8013 (2) nm, b = 1.8775 (4) nm, c = 0.7905(2) nm, beta = 98.22(3)degrees, V = 1.1770(5) nm(3), Z = 2, D-c = 1. 892 g.cm(-3) and F(000) = 656. The final R value is 0.0663 for 1742 observed reflections with Igreater than or equal to2sigma(I). The Pd(II) atoms have trans distorted square-planar PdN4 coordination composed of imino-nitrogen atoms and oximo-nitrogen atoms from the two Schiff base ligands.

引用

页码：947 / 949

页数：3

共 12 条

[1] SIZE AND STABILITY OF CHELATE RINGS IN COORDINATION-COMPOUNDS OF COBALT(II), MANGANESE(II), IRON(III) AND PALLADIUM(II) WITH VICINAL OXIME-IMINE LIGANDS
ALY, MM
[J]. TRANSITION METAL CHEMISTRY, 1990, 15 (02) : 99 - 105
[2] BABAR VJ, 1983, J INDIAN CHEM SOC, V60, P896
[3] BERNSTEIN HJ, 1947, J CHEM PHYS, V1, P284
[4] STRUCTURAL STUDY OF OCTAHEDRAL COBALT(III) COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURE OF TRANS-CHLOROBIS(DIMETHYLGLYOXIMATO)(TRIPHENYLPHOSPHINE)COBALT(III) AND TRANS-CHLOROBIS(DIMETHYLGLYOXIMATO)(AMMINE)-COBALT(III) MONOHYDRATE
BRUCKNER, S
RANDACCIO, L
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (10): : 1017 - 1022
[5] STRUCTURE OF FERROVERDIN
CANDELORO, S
GRDENIC, D
TAYLOR, N
THOMPSON, B
VISWAMITRA, M
HODGKIN, DC
[J]. NATURE, 1969, 224 (5219) : 589 - +
[6] STRUCTURAL CHEMISTRY OF TRANSITION-METAL COMPLEXES OF OXIMES
CHAKRAVORTY, A
[J]. COORDINATION CHEMISTRY REVIEWS, 1974, 13 (01) : 1 - 46
[7] SPECTRA, CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(4-ETHYLIMINO-2,3-PENTANEDIONE-3-OXIMATO) PALLADIUM(II)
DIXIT, NS
MANOHAR, H
PATEL, CC
[J]. INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1977, 13 (07): : 305 - 309
[8] DIXIT NS, 1977, J INDIAN CHEM SOC, V54, P176
[9] Feng YL, 2000, CHEM J CHINESE U, V21, P1455
[10] FENG YL, 1999, THESIS FUZHOU U FUZH

← 1 2 →