Pyrolytic formation and photoluminescence properties of a new layered carbonaceous material with graphite oxide-mimicking characteristics

被引：15

作者：

Bourlinos, A. B. ^{[2
]}

Georgakilas, V. ^{[2
]}

Zboril, R. ^{[3
]}

Bakandritsos, A. ^{[4
]}

Stassinopoulos, A. ^{[5
]}

Anglos, D. ^{[5
]}

Giannelis, E. P. ^{[1
,6
]}

机构：

[1] Cornell Univ, Dept Mat Sci & Engn, Ithaca, NY 14853 USA

[2] NCSR Demokritos, Inst Mat Sci, Athens 15310, Greece

[3] Palacky Univ, Dept Phys Chem, Olomouc 77146, Czech Republic

[4] Univ Patras, Sch Nat Sci, Dept Mat Sci, Rion 26504, Greece

[5] Fdn Res & Technol Hellas, Inst Elect Struct & Laser, GR-71110 Iraklion, Greece

[6] Cornell Univ, Dept Mat Sci & Engn, Ithaca, NY 14853 USA

来源：

CARBON | 2009年 / 47卷 / 02期

关键词：

GRAPHENE; NANOCRYSTALS; FLUORESCENCE; SUSPENSIONS; NANOTUBES; DOTS;

D O I：

10.1016/j.carbon.2008.10.044

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Thermal carbonization of bis(2-chloroethyl)amine hydrochloride at 260 degrees C in air leads to a new, functional layered carbonaceous material that, although different in structure and composition, shares similar characteristics as the well-known graphite oxide. Specifically, the molecularly derived carbonaceous solid is layered with relatively small lateral dimensions, highly dispersible in water providing clear colloidal sols and possesses ion-exchange properties. The carbonaceous solid strongly fluoresces in the visible, when stimulated with a wide range of excitation wavelengths. Overall, the method presents an alternative synthesis towards molecularly derived layered carbonaceous materials with novel properties. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：519 / 526

页数：8

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