Significance of TiCl4 post-treatment on the performance of hydrothermally synthesized titania nanotubes-based dye-sensitized solar cells

被引:8
作者
Akilavasan, Jeganathan [1 ]
Wijeratne, Kosala [1 ]
Gannoruwa, Asangi [1 ]
Alamoud, A. R. M. [2 ]
Bandara, Jayasundera [1 ]
机构
[1] Inst Fundamental Studies, Kandy 20000, CP, Sri Lanka
[2] King Saud Univ, Sustainable Energy Technol SET Ctr, Dept Elect Engn, Riyadh, Saudi Arabia
关键词
TiCl4; treatment; Titania nanotubes; Dye-sensitized solar cells;
D O I
10.1007/s13204-012-0187-4
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this investigation, the effect of concentration of TiCl4 for the post-treatment of hydrothermally synthesized titania nanotubes-based working electrode for dye-sensitized solar cells has been studied. Hydrothermally synthesized TiO2 nanotubes were treated with different concentrations of TiCl4 to investigate the effect of TiCl4 concentration. The solar cell performance increased with the increase in TiCl4 concentration up to 0.5 M and leveled off. The best solar cell showed a short-circuit current density (J(sc)), open-circuit voltage (V-oc), fill factor (FF) and efficiency (eta) of 12.75 mA/cm(2), 795 mV, 69.2 % and 7.04 %, respectively, while untreated TiO2 nanotube showed Jsc, Voc, FF and g of 2.4 mA/cm(2), 899 mV, 78.9 % and 1.7 %, respectively.
引用
收藏
页码:185 / 188
页数:4
相关论文
共 22 条
[1]   Integration of TiO2 nanotube arrays into solid-state dye-sensitized solar cells [J].
Bandara, J. ;
Shankar, K. ;
Basham, J. ;
Wietasch, H. ;
Paulose, M. ;
Varghese, O. K. ;
Grimes, C. A. ;
Thelakkat, M. .
EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS, 2011, 53 (02)
[2]   Physical chemical principles of photovoltaic conversion with nanoparticulate, mesoporous dye-sensitized solar cells [J].
Bisquert, J ;
Cahen, D ;
Hodes, G ;
Rühle, S ;
Zaban, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (24) :8106-8118
[3]   Ultrafast Initial Growth Rate of Self-Assembled TiO2 Nanorod Arrays Fabricated by Ti Anodization [J].
Chang, Yung-Huang ;
Lin, Hsiao-Wei ;
Chen, Chih .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2011, 14 (01) :K1-K4
[4]   Dye-sensitized solar cells with conversion efficiency of 11.1% [J].
Chiba, Yasuo ;
Islam, Ashraful ;
Watanabe, Yuki ;
Komiya, Ryoichi ;
Koide, Naoki ;
Han, Liyuan .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2006, 45 (24-28) :L638-L640
[5]   Novel Preparation Method of TiO2-Nanorod-Based Photoelectrodes for Dye-Sensitized Solar Cells with Improved Light-Harvesting Efficiency [J].
De Marco, Luisa ;
Manca, Michele ;
Giannuzzi, Roberto ;
Malara, Francesco ;
Melcarne, Giovanna ;
Ciccarella, Giuseppe ;
Zama, Isabella ;
Cingolani, Roberto ;
Gigli, Giuseppe .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (09) :4228-4236
[6]   Dye-sensitized solar cells based on TiO2-B nanobelt/TiO2 nanoparticle sandwich-type photoelectrodes with controllable nanobelt length [J].
Dong, Youzhen ;
Pan, Kai ;
Tian, Guohui ;
Zhou, Wei ;
Pan, Qingjiang ;
Xie, Tengfeng ;
Wang, Dejun ;
Fu, Honggang .
DALTON TRANSACTIONS, 2011, 40 (15) :3808-3814
[7]  
Enache PE, 2007, APPL PHYS LETT, V91
[8]   Enhance the optical absorptivity of nanocrystalline TiO2 film with high molar extinction coefficient ruthenium sensitizers for high performance dye-sensitized solar cells [J].
Gao, Feifei ;
Wang, Yuan ;
Shi, Dong ;
Zhang, Jing ;
Wang, Mingkui ;
Jing, Xiaoyan ;
Humphry-Baker, Robin ;
Wang, Peng ;
Zakeeruddin, Shaik M. ;
Graetzel, Michael .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (32) :10720-10728
[9]   Electrophoretic deposition of titanate nanotubes from commercial titania nanoparticles: Application to dye-sensitized solar cells [J].
Kim, Gil-Sung ;
Seo, Hyung-Kee ;
Godble, V. P. ;
Kim, Young-Soon ;
Yang, O-Bong ;
Shin, Hyung-Shik .
ELECTROCHEMISTRY COMMUNICATIONS, 2006, 8 (06) :961-966
[10]   Charge Transport Characteristics of High Efficiency Dye-Sensitized Solar Cells Based on Electrospun TiO2 Nanorod Photoelectrodes [J].
Lee, Byung Hong ;
Song, Mi Yeon ;
Jang, Sung-Yeon ;
Jo, Seong Mu ;
Kwak, Seong-Yeop ;
Kim, Dong Young .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (51) :21453-21457