Integrating graphene oxide into layers of PVDF/PVDF@cross-linked sodium alginate/polyamide membrane for efficiently enhancing desalination performances

被引:7
|
作者
Mohammadi, Zohreh [1 ]
Seyed Dorraji, Mir Saeed [1 ]
Ahmadi, Arsalan [1 ,2 ]
Tarighati Sareshkeh, Abdolreza [1 ]
Rasoulifard, Mohammad Hossein [1 ]
机构
[1] Univ Zanjan, Dept Chem, Appl Chem Res Lab, Fac Sci, Zanjan, Iran
[2] Absamin Water Treatment Co, Res & Dev Lab, Karaj, Iran
关键词
FILM COMPOSITE MEMBRANES; NANOFILTRATION MEMBRANES; MECHANICAL-PROPERTIES; POLYAMIDE MEMBRANES; NANOCOMPOSITE; SEPARATION; IONS; GO;
D O I
10.1038/s41598-022-21316-y
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The membrane modules of the water treatment system are faced costly damages; thereby executing pre-desalination units based on Nanofiltration (NF) could prevent these suffers, and improve the permeated water flux (PWF) and salt rejection (SR). Hence, we focused on the construction of a novel ternary-layer NF membrane through "electrospinning Polyvinylidene Fluoride (PVDF) (as bottom layer)", "generating middle layer by electrospinning PVDF along with, the implementation cross-linking after electrospraying Sodium Alginate", and "synthesizing Polyamide (as top layer) through interfacial polymerization". More importantly, it anticipated that the Taguchi statistical method can expeditiously optimize the effects of Graphene Oxide nano-sheets (GOns) on water-dependent properties, such as PWF and SR. Astonishingly, the desalination capabilities significantly improved, when the top, middle, and bottom layers simultaneously had 1, 0.1, and 0.1 wt.% of GOns, respectively. Overall, comparing the performances between the optimized sample containing low-dosage and without GOns demonstrated the PWF ameliorated from 6.68 to 20.36 L/m(2) h; also, the SR ability remained on an incremental basis as NaCl < MgCl2 < MgSO4 under 6 bar pressure. Manifestly, these authentic results denoted promising, innovative, and large-scaling insights when effectual PWF and SR be necessary.
引用
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页数:12
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