Solution processed polymer light-emitting diodes with single layer graphene anode

被引:2
作者
Ha, Jaeheung [1 ,2 ]
Park, Subeom [3 ]
Kim, Donghyun [1 ,2 ]
Ryu, Jaechul [4 ,5 ]
Lee, Changhee [1 ,2 ]
Hong, Byung Hee [2 ,3 ]
Hong, Yongtaek [1 ,2 ]
机构
[1] Seoul Natl Univ, Dept Elect Engn & Comp Sci, Seoul, South Korea
[2] Seoul Natl Univ, ISRC, Seoul, South Korea
[3] Seoul Natl Univ, Dept Chem, Seoul, South Korea
[4] Sungkyunkwan Univ, SAINT, Suwon, South Korea
[5] Sungkyunkwan Univ, Ctr Human Interface Nano Technol HINT, Suwon, South Korea
来源
ORGANIC LIGHT EMITTING MATERIALS AND DEVICES XVI | 2012年 / 8476卷
关键词
Graphene; PLEDs; UV ozone treatment; Work function;
D O I
10.1117/12.928821
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We fabricated the graphene based PLEDs that had the structure of glass / single layer graphene with Ag auxiliary electrode (anode) / PEDOT:PSS (HITL) / SPG-01T(Green polymer lighting material from Merck, EML) / Ca (EIL) / Al (Cathode). Single layer graphene was synthesized on copper foil by thermal CVD process, and then transferred to glass substrate by PMMA stamp. Formation of single layer graphene was confirmed from AFM, Raman spectroscopy, and UV-vis spectroscopy measurements. Graphene film was treated through a shadow mask for 15 minutes in UV ozone chamber to obtain anode pattern. After that, the patterned graphene layer was exposed to UV ozone to control its work function, which was found to be increased by 0.18eV and 0.27eV after 2.5 minutes and 5 minutes treatment, respectively. On the graphene layer, PEDOT:PSS and SPG-01T were consecutively spin-coated and annealed in the globe box. Ca and Al metal layer was deposited by thermal evaporation. Our graphene based PLEDs had the current efficiency of 9.73 cd/A and the power efficiency of 5.51 lm/W while our reference device with ITO anode showed the efficiencies of 12.5 cd/A and 8.01 lm/W.
引用
收藏
页数:4
相关论文
共 9 条
[1]  
Bae S, 2010, NAT NANOTECHNOL, V5, P574, DOI [10.1038/nnano.2010.132, 10.1038/NNANO.2010.132]
[2]  
Brabec C, 2008, ORGANIC PHOTOVOLTAIC, P251
[3]   Anisotropic Etching and Nanoribbon Formation in Single-Layer Graphene [J].
Campos, Leonardo C. ;
Manfrinato, Vitor R. ;
Sanchez-Yamagishi, Javier D. ;
Kong, Jing ;
Jarillo-Herrero, Pablo .
NANO LETTERS, 2009, 9 (07) :2600-2604
[4]   Continuous, Highly Flexible, and Transparent Graphene Films by Chemical Vapor Deposition for Organic Photovoltaics [J].
De Arco, Lewis Gomez ;
Zhang, Yi ;
Schlenker, Cody W. ;
Ryu, Koungmin ;
Thompson, Mark E. ;
Zhou, Chongwu .
ACS NANO, 2010, 4 (05) :2865-2873
[5]   Large-scale pattern growth of graphene films for stretchable transparent electrodes [J].
Kim, Keun Soo ;
Zhao, Yue ;
Jang, Houk ;
Lee, Sang Yoon ;
Kim, Jong Min ;
Kim, Kwang S. ;
Ahn, Jong-Hyun ;
Kim, Philip ;
Choi, Jae-Young ;
Hong, Byung Hee .
NATURE, 2009, 457 (7230) :706-710
[6]   Rapid Trench Channeling of Graphenes with Catalytic Silver Nanoparticles [J].
Severin, N. ;
Kirstein, S. ;
Sokolov, I. M. ;
Rabe, J. P. .
NANO LETTERS, 2009, 9 (01) :457-461
[7]   Multilayered graphene used as anode of organic light emitting devices [J].
Sun, T. ;
Wang, Z. L. ;
Shi, Z. J. ;
Ran, G. Z. ;
Xu, W. J. ;
Wang, Z. Y. ;
Li, Y. Z. ;
Dai, L. ;
Qin, G. G. .
APPLIED PHYSICS LETTERS, 2010, 96 (13)
[8]   Organic Light-Emitting Diodes on Solution-Processed Graphene Transparent Electrodes [J].
Wu, Junbo ;
Agrawal, Mukul ;
Becerril, Hector A. ;
Bao, Zhenan ;
Liu, Zunfeng ;
Chen, Yongsheng ;
Peumans, Peter .
ACS NANO, 2010, 4 (01) :43-48
[9]   Photocatalytic Patterning and Modification of Graphene [J].
Zhang, Liming ;
Diao, Shuo ;
Nie, Yufeng ;
Yan, Kai ;
Liu, Nan ;
Dai, Boya ;
Xie, Qin ;
Reina, Alfonso ;
Kong, Jing ;
Liu, Zhongfan .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (08) :2706-2713