Isobaric Vapor-Liquid Equilibria for Binary Mixtures of Z,E-2-Methyl-2-butenenitrile, R,S-4-Vinyl-1-cyclohexene, and Z,E-3-Pentenenitrile

被引:3
作者
He, Zhijian [1 ]
Song, Hang [2 ]
Wang, Zhixia [2 ]
Cao, Yu [1 ]
机构
[1] Mianyang Normal Univ, Coll Life Sci & Biotechnol, Mianyang 621000, Peoples R China
[2] Sichuan Univ, Sch Chem Engn, Chengdu 610065, Peoples R China
关键词
2-METHYL-2-BUTENENITRILE; ACID;
D O I
10.1021/acs.jced.6b00388
中图分类号
O414.1 [热力学];
学科分类号
摘要
Vapor-liquid equilibrium (VLE) at P = 50 and 100 kPa data for binary systems,(Z,E-2-methyl-2-butenenitrile + R,S-4-vinyl-1-cyclohexene) and system (Z,E-2-methyl-2-butenenitrile + Z,E-3-pentenenitrile) was determined. All experimental VLE data were tested by the point test and were proven to be thermodynamically consistent. Activity coefficient correlation models (Wilson and NRTL models) were used to calculate all VLE experimental data. The model parameters were obtained by correlating the experimental data. The VLE data calculated from parameters were consistent with the experimental values.
引用
收藏
页码:3466 / 3471
页数:6
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