Orientation of adsorbed polar molecules (dipoles) in external electrostatic field

被引:3
|
作者
Gabovich, A. M. [1 ]
Voitenko, A., I [1 ]
机构
[1] Inst Phys, 46 Nauky Ave, UA-03028 Kiev, Ukraine
关键词
electric dipole; electrostatic field; adsorption; bistable switch; polar molecule; interface phenomena; image forces; METAL-SEMICONDUCTOR JUNCTIONS; SURFACE STRUCTURE; CONICAL-WELL; IMAGE FORCES; ELECTRONS; WATER; STATES; MODEL; PLASMONS;
D O I
10.1088/1361-648X/abb997
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
A model is proposed in the framework of classical electrostatics to describe the behavior of an adsorbed polar molecule near the plane interface between two insulators under the action of an external electrostatic field. The molecule is considered as a permanent point dipole that polarizes the interface and interacts with it through electrostatic image forces. The latter and the applied field try to reorient the dipole in a competitive manner. The system behavior turns out to be rather complicated: it may show a bistable character with a hysteresis (a switch). Such a switch can serve as an element in a memory network made of adsorbed molecules.
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页数:11
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