Two-phase versus two-stage versus multi-phase lithiation kinetics in silicon

被引：18

作者：

Cui, Zhiwei ^{[1
]}

Gao, Feng ^{[1
]}

Qu, Jianmin ^{[1
,2
]}

机构：

[1] Northwestern Univ, Dept Civil & Environm Engn, Evanston, IL 60208 USA

[2] Northwestern Univ, Dept Mech Engn, Evanston, IL 60208 USA

来源：

APPLIED PHYSICS LETTERS | 2013年 / 103卷 / 14期

关键词：

REACTION CONTROLLED DIFFUSION; LITHIUM-ION BATTERIES; AMORPHOUS-SILICON; ELECTROCHEMICAL LITHIATION; NANOWIRES; ANODES; ELECTRODES; SOLIDS;

D O I：

10.1063/1.4824064

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

We classify the lithiation process into three types, namely, two-phase, two-stage, and multi-phase lithiation. We found that under a given charging rate, smaller electrochemical Biot number of beta will likely to result in two-phase lithiation, while larger beta may lead to multi-phase lithiation. For the film anode, intermediate beta, or intermediate charging rate, will yield two-stage lithiation, and the Li concentration during the first stage of the lithiation is determined by the relationship between beta and the charging rate (or more precisely the Li flux supplied to the Si/LixSi phase interface). Such two-stage lithiation does not occur in the particle or fiber anode. (C) 2013 AIP Publishing LLC.

引用

页数：4

共 18 条

[1] Amorphous silicon as a possible anode material for Li-ion batteries [J].

Bourderau, S ;

Brousse, T ;

Schleich, DM .

JOURNAL OF POWER SOURCES, 1999, 81 :233-236

[2] High-performance lithium battery anodes using silicon nanowires [J].

Chan, Candace K. ;

Peng, Hailin ;

Liu, Gao ;

McIlwrath, Kevin ;

Zhang, Xiao Feng ;

Huggins, Robert A. ;

Cui, Yi .

NATURE NANOTECHNOLOGY, 2008, 3 (01) :31-35

[3] First Principles Model of Amorphous Silicon Lithiation [J].

Chevrier, V. L. ;

Dahn, J. R. .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (06) :A454-A458

[4] Real-Time Measurement of Stress and Damage Evolution during Initial Lithiation of Crystalline Silicon [J].

Chon, M. J. ;

Sethuraman, V. A. ;

McCormick, A. ;

Srinivasan, V. ;

Guduru, P. R. .

PHYSICAL REVIEW LETTERS, 2011, 107 (04)

[5] Crystalline-Amorphous Core-Shell Silicon Nanowires for High Capacity and High Current Battery Electrodes [J].

Cui, Li-Feng ;

Ruffo, Riccardo ;

Chan, Candace K. ;

Peng, Hailin ;

Cui, Yi .

NANO LETTERS, 2009, 9 (01) :491-495

[6] On the perturbation solution of interface-reaction controlled diffusion in solids [J].

Cui, Zhi-Wei ;

Gao, Feng ;

Qu, Jian-Min .

ACTA MECHANICA SINICA, 2012, 28 (04) :1049-1057

[7] Interface-reaction controlled diffusion in binary solids with applications to lithiation of silicon in lithium-ion batteries [J].

Cui, Zhiwei ;

Gao, Feng ;

Qu, Jianmin .

JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS, 2013, 61 (02) :293-310

[8] A finite deformation stress-dependent chemical potential and its applications to lithium ion batteries [J].

Cui, Zhiwei ;

Gao, Feng ;

Qu, Jianmin .

JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS, 2012, 60 (07) :1280-1295

[9] A second nearest-neighbor embedded atom method interatomic potential for Li-Si alloys [J].

Cui, Zhiwei ;

Gao, Feng ;

Cui, Zhihua ;

Qu, Jianmin .

JOURNAL OF POWER SOURCES, 2012, 207 :150-159

[10] Stress relaxation through interdiffusion in amorphous lithium alloy electrodes [J].

Gao, Y. F. ;

Cho, M. ;

Zhou, M. .

JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS, 2013, 61 (02) :579-596

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