Nanocomposites Derived from Polyoxometalate Complexes of Copper(II) and Nickel(II) with Au(0)

被引：1

作者：

Barna, A. V. ^{[1
]}

Lampeka, Ya. D. ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, LV Pisarzhevskii Inst Phys Chem, UA-03028 Kiev, Ukraine

来源：

THEORETICAL AND EXPERIMENTAL CHEMISTRY | 2013年 / 49卷 / 05期

关键词：

tetraamine complexes; copper; nickel; polyoxometalates; redox reactions; nanoparticles; gold; METAL-ORGANIC-FRAMEWORK; SILVER NANOPARTICLES; REDUCTION;

D O I：

10.1007/s11237-013-9335-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A heterophase interaction of reduced polyoxometalate (POM) compounds containing copper(II) and nickel(II) amine complexes as the cationic component with aqueous solutions of H[AuCl4] is accompanied by adsorption of the tetrachloroaurate anion by the POM matrix and leads to the formation of products containing nanoparticles of metallic gold. The concentrations of the components and nature of the reducing agent significantly affect the structure of the composites formed.

引用

页码：340 / 345

页数：6

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