Electromagnetic absorption properties of graphene/Fe nanocomposites

被引:101
作者
Chen, Yujin [1 ]
Lei, Zhenyu [1 ]
Wu, Hongyu [1 ]
Zhu, Chunling [2 ]
Gao, Peng [2 ]
Ouyang, Qiuyun [1 ]
Qi, Li-Hong [1 ]
Qin, Wei [3 ]
机构
[1] Harbin Engn Univ, Coll Sci, Key Lab Infiber Integrated Opt, Minist Educ China, Harbin 150001, Peoples R China
[2] Harbin Engn Univ, Coll Mat Sci & Chem Engn, Harbin 150001, Peoples R China
[3] Harbin Inst Technol, Sch Mat Sci & Engn, Harbin 150001, Peoples R China
基金
中国国家自然科学基金;
关键词
Composites; Interfaces; Chemical synthesis; Dielectric properties; Magnetic properties; CORE/SHELL NANORODS SYNTHESIS; MICROWAVE-ABSORPTION; FE3O4; NANOPARTICLES; CARBON NANOTUBES; RESONANCE;
D O I
10.1016/j.materresbull.2013.05.020
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Graphene (G)/Fe nanocomposites with ferromagnetic properties at room temperature were fabricated by a facile and green method. Transmission electron microscope (TEM) and atomic force microscopy (AFM) amylases reveal that the alpha-Fe nanoparticles with a diameter of only about 10 nm were uniformly dispersed over the surface of the graphene sheets. Compared with other magnetic materials and the graphene, the nanocomposites exhibited significantly enhanced electromagnetic absorption properties. The maximum reflection loss to electromagnetic wave was up to-31.5 dB at a frequency of 14.2 GHz for G/Fe nanocomposites with a thickness of 2.5 mm. Importantly, the addition of the nanocomposites is only about 20 wt.% in the matrix. The enhanced mechanism is discussed and it is related to high surface areas of G/Fe nanocomposites, interfacial polarizations between graphene and iron, synergetic effect and efficient dispersity of magnetic NPs. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3362 / 3366
页数:5
相关论文
共 29 条
[1]   Green Approach To Prepare Graphene-Based Composites with High Microwave Absorption Capacity [J].
Bai, Xin ;
Zhai, Yinghao ;
Zhang, Yong .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (23) :11673-11677
[2]   One-step chemical vapor synthesis of Ni/graphene nanocomposites with excellent electromagnetic and electrocatalytic properties [J].
Cao, Yu ;
Su, Qingmei ;
Che, Renchao ;
Du, Gaohui ;
Xu, Bingshe .
SYNTHETIC METALS, 2012, 162 (11-12) :968-973
[3]   Fabrication and microwave absorption of carbon nanotubes/CoFe2O4 spinel nanocomposite -: art. no. 033105 [J].
Che, RC ;
Zhi, CY ;
Liang, CY ;
Zhou, XG .
APPLIED PHYSICS LETTERS, 2006, 88 (03) :1-3
[4]   Microwave absorption enhancement and complex permittivity and permeability of Fe encapsulated within carbon nanotubes [J].
Che, RC ;
Peng, LM ;
Duan, XF ;
Chen, Q ;
Liang, XL .
ADVANCED MATERIALS, 2004, 16 (05) :401-+
[5]   A novel preparation and surface decorated approach for α-Fe nanoparticles by chemical vapor-liquid reaction at low temperature [J].
Chen, YJ ;
Cao, MS ;
Tian, Q ;
Wang, TH ;
Zhu, J .
MATERIALS LETTERS, 2004, 58 (09) :1481-1484
[6]   Porous Fe3O4/Carbon Core/Shell Nanorods: Synthesis and Electromagnetic Properties [J].
Chen, Yu-Jin ;
Xiao, Gang ;
Wang, Tie-Shi ;
Ouyang, Qiu-Yun ;
Qi, Li-Hong ;
Ma, Yang ;
Gao, Peng ;
Zhu, Chun-Ling ;
Cao, Mao-Sheng ;
Jin, Hai-Bo .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (28) :13603-13608
[7]   Synthesis, Multi-Nonlinear Dielectric Resonance, and Excellent Electromagnetic Absorption Characteristics of Fe3O4/ZnO Core/Shell Nanorods [J].
Chen, Yu-Jin ;
Zhang, Fan ;
Zhao, Guo-gang ;
Fang, Xiao-yong ;
Jin, Hai-Bo ;
Gao, Peng ;
Zhu, Chun-Ling ;
Cao, Mao-Sheng ;
Xiao, G. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (20) :9239-9244
[8]   Porous Fe3O4/SnO2 Core/Shell Nanorods: Synthesis and Electromagnetic Properties [J].
Chen, Yu-Jin ;
Gao, Peng ;
Wang, Rui-Xuan ;
Zhu, Chun-Ling ;
Wang, Li-Jiao ;
Cao, Mao-Sheng ;
Jin, Hai-Bo .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (23) :10061-10064
[9]  
Choucair M, 2009, NAT NANOTECHNOL, V4, P30, DOI [10.1038/nnano.2008.365, 10.1038/NNANO.2008.365]
[10]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191