Volumetric Properties of 1,3-Dioxolane plus Toluene plus o- or p-Xylene Ternary Mixtures at 25.00 °C and Atmospheric Pressure

被引：1

作者：

Kumar, Satish ^{[1
]}

Sharma, V. K. ^{[2
]}

Moon, Il ^{[1
]}

机构：

[1] Yonsei Univ, Dept Chem & Biomol Engn, Seoul 120749, South Korea

[2] Maharshi Dayanand Univ, Dept Chem, Rohtak 124001, Haryana, India

来源：

JOURNAL OF SOLUTION CHEMISTRY | 2013年 / 42卷 / 05期

关键词：

1,3-dioxolane; Excess molar volume; Graph theory; Connectivity parameter; EXCESS ISENTROPIC COMPRESSIBILITIES; TOPOLOGICAL INVESTIGATIONS; MOLECULAR-INTERACTIONS; BINARY-MIXTURES; THERMODYNAMIC PROPERTIES; INCLUDING SOLUTIONS; MOLAR VOLUMES; NONELECTROLYTES; 1,4-DIOXANE; ENTHALPIES;

D O I：

10.1007/s10953-013-0017-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Excess molar volumes, V-123(E), of 1, 3-dioxolane (1) + toluene (2) + o- or p-xylene (3) ternary mixtures have been determined dilatometrically over the entire composition range at 298.15 K. For thermodynamic consistency the experimental values were fitted to Redlich-Kister Equation. The V-123(E) values of 1, 3-dioxolane (1) + toluene (2) + o- or p-xylene (3) ternary mixtures have been found to be negative over the whole composition range. It has been observed that V-123(E) values calculated by graph theory are of the same sign and magnitude with respect to their experimental values.

引用

页码：936 / 944

页数：9

共 21 条

[1]

[Anonymous], 1986, PHYS PROPERTIES METH

[2] Excess molar enthalpies and excess molar volumes of binary mixtures containing 1,3-dioxolane or 1,4-dioxane plus pine resins at (298.15 and 313.15) K and at atmospheric pressure [J].

Francesconi, R ;

Castellari, C ;

Comelli, F .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2001, 46 (03) :577-581

[3] Densities, excess molar volumes, viscosities, speeds of sound, excess isentropic compressibilities, and relative permittivities for CmH2m+1(OCH2CH2)nOH (m=1 or 2 or 4 and n=1) plus benzene, plus toluene, plus (o-, m-, and p-) xylenes, plus ethylbenzene, and plus cyclohexane [J].

George, J ;

Sastry, NV .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2003, 48 (04) :977-989

[4] THERMODYNAMIC PROPERTIES OF LIQUIDS, INCLUDING SOLUTIONS .1. INTERMOLECULAR ENERGIES IN MONOTONIC LIQUIDS AND THEIR MIXTURES [J].

HUGGINS, ML .

JOURNAL OF PHYSICAL CHEMISTRY, 1970, 74 (02) :371-&

[5] THERMODYNAMIC PROPERTIES OF LIQUIDS, INCLUDING SOLUTIONS .2. POLYMER SOLUTIONS CONSIDERED AS DITONIC SYSTEMS [J].

HUGGINS, ML .

POLYMER, 1971, 12 (06) :389-&

[6]

Kalra KC, 1998, INDIAN J CHEM A, V37, P308

[7]

Katoch A, 1998, THESIS MAHARISHI DAY

[8]

Kier LB., 1976, Molecular connectivity in chemistry and drug research

[9] Speed of Sound and Excess Isentropic Compressibility of 1,3-Dioxolane or 1,4-Dioxane + Butan-1-ol or + Butan-2-ol Binary Mixtures at 308.15 K and Atmospheric Pressure [J].

Kumar, Satish ;

Sharma, V. K. ;

Moon, Il .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (18) :8365-8368

[10] Thermodynamic Investigation of Molecular Interactions in 1,3-Dioxolane or 1,4-Dioxane+Benzene or Toluene plus Formamide or plus N,N-Dimethylformamide Ternary Mixtures at 308.15 K and Atmospheric Pressure [J].

Kumar, Satish ;

Sharma, V. K. ;

Yadav, J. S. ;

Moon, Il .

JOURNAL OF SOLUTION CHEMISTRY, 2010, 39 (05) :680-691

← 1 2 3 →