Kinetic interpretation of multi-stage self-ignition of paraffin hydrocarbons

被引：0
|
作者：
Basevich, VY [1 ]
Vedeneev, VI [1 ]
Arutyunov, VS [1 ]
机构：
[1] Russian Acad Sci, N Semenov Inst Chem Phys, Moscow 11977, Russia
来源：
CHEMICAL PHYSICS REPORTS | 1998年 / 17卷 / 05期
关键词：
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
Numerical modeling of ethane oxidation with separated self-ignition stages: cool flame (with chain branching via ethyl hydroperoxide (C2H5O2H), methyl hydroperoxide (CH3O2H), and partly hydrogen peroxide (H2O2) decomposition), stage preceding the hot flame (with chain branching via hydrogen peroxide decomposition alone), and hot flame ignition, is performed. A kinetic interpretation of the process based on the concept of multi-stage self-ignition of paraffin hydrocarbons is suggested.
引用
收藏
页码：917 / 926
页数：10
相关论文
共 50 条
  • [1] Modeling the blue flames during multi-stage self-ignition of acetaldehyde
    Basevich, V.Ya.
    Vedeneev, V.I.
    Romanovich, L.B.
    2003, Nauka, Moscow (22):
  • [2] MECHANISM OF COLD FLAME FORMATION UNDER OXIDATION AND SELF-IGNITION OF PARAFFIN HYDROCARBONS
    MULYAVA, MP
    SHCHEMELEV, GV
    KUCHER, RV
    DOPOVIDI AKADEMII NAUK UKRAINSKOI RSR SERIYA B-GEOLOGICHNI KHIMICHNI TA BIOLOGICHNI NAUKI, 1985, (04): : 53 - 56
  • [3] SELF-IGNITION OF HYDROCARBONS IN LARGER VOLUMES
    PANCHENK.GM
    MALYSHEV, VV
    MAKARENK.VV
    GRIGOREV, VA
    PUSTYREV, OG
    ZHURNAL FIZICHESKOI KHIMII, 1972, 46 (09): : 2286 - &
  • [4] REACTIONS LEADING TO THE FORMATION OF BLUE AND DARK-BLUE FLAME IN OXIDATION AND SELF-IGNITION OF PARAFFIN HYDROCARBONS
    MULYAVA, MP
    SHCHEMELEV, GV
    CUTOR, IM
    KUCHER, RV
    DOPOVIDI AKADEMII NAUK UKRAINSKOI RSR SERIYA B-GEOLOGICHNI KHIMICHNI TA BIOLOGICHNI NAUKI, 1986, (04): : 50 - 53
  • [5] Detailed numerical simulations for the multi-stage self-ignition process of n-decane single droplets with complex chemistry
    S. Schnaubelt
    O. Moriue
    Ch Eigenbrod
    H. J. Rath
    Microgravity Science and Technology, 2001, 13 : 20 - 23
  • [6] Detailed numerical simulations for the multi-stage self-ignition process of n-decane single droplets with complex chemistry
    Schnaubelt, S
    Moriue, O
    Eigenbrod, C
    Rath, HJ
    MICROGRAVITY SCIENCE AND TECHNOLOGY, 2001, 13 (01) : 20 - 23
  • [7] CONCENTRATION LIMITS OF SELF-IGNITION OF HYDROCARBONS AND HYDROCARBON FUELS
    PANCHENK.GM
    MAKARENK.VV
    GRIGOREV, VA
    MALYSHEV, VV
    PUSTYREV, OG
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY,USSR, 1972, 46 (02): : 217 - &
  • [8] CONCENTRATION LIMITS OF SELF-IGNITION OF HYDROCARBONS AND HYDROCARBON FUELS
    PANCHENK.GM
    MAKARENK.VV
    GRIGOREV, VA
    MALYSHEV, VV
    PUSTYREV, OG
    ZHURNAL FIZICHESKOI KHIMII, 1972, 62 (02): : 374 - &
  • [9] Kinetic Model and Experiment for Self-Ignition of Triethylaluminum and Triethylborane Droplets in Air
    Frolov, Sergey M. M.
    Basevich, Valentin Y. Y.
    Belyaev, Andrey A. A.
    Shamshin, Igor O. O.
    Aksenov, Viktor S. S.
    Frolov, Fedor S. S.
    Storozhenko, Pavel A. A.
    Guseinov, Shirin L. L.
    MICROMACHINES, 2022, 13 (11)
  • [10] SELF-IGNITION TEMPERATURES OF MATERIALS FROM KINETIC-REACTION DATA
    GROSS, D
    ROBERTSON, AF
    JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS, 1958, 61 (05): : 413 - 417
12345