Radical-radical cross coupling reactions of photo-excited fluorenones

被引：17

作者：

Sharma, Simmi ^{[1
]}

Sultan, Shaista ^{[1
]}

Devari, Shekaraiah ^{[1
]}

Shah, Bhahwal Ali ^{[1
]}

机构：

[1] Indian Inst Integrat Med, CSIR, Nat Prod Microbes, Acad Sci & Innovat Res, Canal Rd, Jammu 180001, India

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2016年 / 14卷 / 40期

关键词：

SINGLE-ELECTRON-TRANSFER; DYNAMIC KINETIC RESOLUTION; CATALYZED DEHYDROGENATIVE CYCLIZATION; AROMATIC CARBONYL-COMPOUNDS; C-H FUNCTIONALIZATION; ALPHA-AMINO RADICALS; VISIBLE-LIGHT; CARBOXYLIC-ACIDS; ENANTIOSELECTIVE SYNTHESIS; MERGING PHOTOREDOX;

D O I：

10.1039/c6ob01879c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Radical-radical cross coupling reactions of photoexcited 9-fluorenones have been accomplished for the first time, leading to the synthesis of 9-alkyl, pyrollidinyl and spiro-THF derivatives of 9-fluorenones. The method also reveals, for the first time, the behaviour of ketyl radicals in decarboxyaltive alkylation and ring expansion reactions.

引用

页码：9645 / 9649

页数：5

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