Synthesis of porous LiMn2O4 hollow nanofibers by electrospinning with extraordinary lithium storage properties

被引:89
作者
Jayaraman, Sundaramurthy [2 ,3 ]
Aravindan, Vanchiappan [1 ]
Kumar, Palaniswamy Suresh [4 ]
Ling, Wong Chui [1 ]
Ramakrishna, Seeram [2 ,3 ]
Madhavi, Srinivasan [1 ,5 ]
机构
[1] Nanyang Technol Univ, ERI N, Singapore 637553, Singapore
[2] Natl Univ Singapore, Ctr Nanofibers & Nanotechnol, Singapore 117576, Singapore
[3] Natl Univ Singapore, Dept Mech Engn, Singapore 117576, Singapore
[4] Ngee Ann Polytech, Ctr Innovat, Singapore 599489, Singapore
[5] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
基金
新加坡国家研究基金会;
关键词
CATHODE MATERIALS; SPINEL LIMN2O4; PERFORMANCE;
D O I
10.1039/c3cc43874k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the extraordinary lithium storage performance of porous LiMn2O4 hollow nanofibers synthesized by electrospinning technique. The electrospun LiMn2O4 hollow nanofibers retained 87% of initial reversible capacity after 1250 cycles at the 1 C rate. Further, excellent cycling profiles at 55 degrees C and cubic spinel to tetragonal phase transformation are also noted.
引用
收藏
页码:6677 / 6679
页数:3
相关论文
共 20 条
[1]   Synthesis and enhanced electrochemical performance of Li2CoPO4F cathodes under high current cycling [J].
Amaresh, S. ;
Kim, G. J. ;
Karthikeyan, K. ;
Aravindan, V. ;
Chung, K. Y. ;
Cho, B. W. ;
Lee, Y. S. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (34) :11904-11909
[2]   LiMnPO4 - A next generation cathode material for lithium-ion batteries [J].
Aravindan, Vanchiappan ;
Gnanaraj, Joe ;
Lee, Yun-Sung ;
Madhavi, Srinivasan .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (11) :3518-3539
[3]   Lithium-Ion Conducting Electrolyte Salts for Lithium Batteries [J].
Aravindan, Vanchiappan ;
Gnanaraj, Joe ;
Madhavi, Srinivasan ;
Liu, Hua-Kun .
CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (51) :14326-14346
[4]   Batteries for Electric and Hybrid-Electric Vehicles [J].
Cairns, Elton J. ;
Albertus, Paul .
ANNUAL REVIEW OF CHEMICAL AND BIOMOLECULAR ENGINEERING, VOL 1, 2010, 1 :299-320
[5]   Electrospinning: designed architectures for energy conversion and storage devices [J].
Cavaliere, Sara ;
Subianto, Surya ;
Savych, Iuliia ;
Jones, Deborah J. ;
Roziere, Jacques .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (12) :4761-4785
[6]   The analysis and implementation of the Double-Line maximum power point tracking method [J].
Cheng, Zhao-Liang ;
Liu, Shu-Qin ;
Yu, Wen-Tao ;
Weng, He-Zhang ;
Zhang, Wen-Shan .
ELECTRICAL POWER & ENERGY SYSTEMS, PTS 1 AND 2, 2012, 516-517 :797-803
[7]   Cathode materials: A personal perspective [J].
Goodenough, John B. .
JOURNAL OF POWER SOURCES, 2007, 174 (02) :996-1000
[8]   A Truncated Manganese Spinel Cathode for Excellent Power and Lifetime in Lithium-Ion Batteries [J].
Kim, Joo-Seong ;
Kim, KyungSu ;
Cho, Woosuk ;
Shin, Weon Ho ;
Kanno, Ryoji ;
Choi, Jang Wook .
NANO LETTERS, 2012, 12 (12) :6358-6365
[9]   High performance lithium-ion cells using one dimensional electrospun TiO2 nanofibers with spinel cathode [J].
Kumar, P. Suresh ;
Aravindan, V. ;
Sundaramurthy, J. ;
Thavasi, V. ;
Mhaisalkar, S. G. ;
Ramakrishna, Seeram ;
Madhavi, S. .
RSC ADVANCES, 2012, 2 (21) :7983-7987
[10]   One-step, low-temperature route for the preparation of spinel LiMn2O4 as a cathode material for rechargeable lithium batteries [J].
Liang, YY ;
Bao, SJ ;
He, BL ;
Zhou, WJ ;
Li, HL .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (10) :A2030-A2034