Tetrachlorobis(N,N,N'N'-tetramethylethylenediamine-N,N') thorium(IV)

被引：5

作者：

Rabinovich, D ^{[1
]}

Schimek, GL ^{[1
]}

Pennington, WT ^{[1
]}

Nielsen, JB ^{[1
]}

Abney, KD ^{[1
]}

机构：

[1] CLEMSON UNIV,DEPT CHEM,CLEMSON,SC 29634

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S0108270196012796

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [ThCl4(C6H16N2)(2)], displays an approximate dodecahedral geometry in the solid state, with the Th atom binding to four Cl ligands and to the four N atoms of two tetramethylethylenediamine ligands. The Th-Cl and Th-N distances are in the ranges 2.683 (3)-2.692 (3) and 2.800 (7)-2.825 (9) Angstrom, respectively.

引用

收藏

页码：191 / 193

页数：3

相关论文

共 14 条

[1] URANIUM(IV) AND THORIUM(IV) HALIDE AND PSEUDOHALIDE COMPLEXES WITH SUBSTITUTED AMIDE AND UREA LIGANDS [J].

ALDAHER, AGM ;

BAGNALL, KW ;

BENETOLLO, F ;

POLO, A ;

BOMBIERI, G .

JOURNAL OF THE LESS-COMMON METALS, 1986, 122 :167-173

[2]

BEYERS JJ, 1992, ACTA CRYSTALLOGR C, V48, P2023

[3]

CROMER DT, 1974, INT TABLES XRAY CRYS, V4, P149

[4] A 7-CO-ORDINATE ACTINOID COMPLEX - CRYSTAL AND MOLECULAR-STRUCTURE OF TETRACHLOROTRIS(TRIMETHYLAMINE)THORIUM(IV) [J].

DREW, MGB ;

WILLEY, GR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (04) :727-729

[5] PREPARATION AND SYNTHETIC UTILITY OF MCL(4)(ME(2)NCH(2)CH(2)NME(2))(2), WHERE M IS URANIUM OR THORIUM [J].

EDWARDS, PG ;

WEYDERT, M ;

PETRIE, MA ;

ANDERSEN, RA .

JOURNAL OF ALLOYS AND COMPOUNDS, 1994, 213 :11-14

[6] STEREOCHEMISTRY OF DISCRETE 8-COORDINATION .1. BASIC ANALYSIS [J].

HOARD, JL ;

SILVERTON, JV .

INORGANIC CHEMISTRY, 1963, 2 (02) :235-&

[7]

Larson A.C., 1970, CRYSTALLOGRAPHIC COM, P291

[8]

*MOL STRUCT CORP, 1988, MSC AFC DIFFR CONTR

[9]

*MOL STRUCT CORP, 1989, TEXSAN SINGL CRYST S

[10] A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].

NORTH, ACT ;

PHILLIPS, DC ;

MATHEWS, FS .

ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :351-&