Addition of Hydrogen or Ammonia to a Low-Valent Group 13 Metal Species at 25°C and 1 Atmosphere

被引：108
作者：
Zhu, Zhongliang [1 ]
Wang, Xinping [1 ]
Peng, Yang [1 ]
Lei, Hao [1 ]
Fettinger, James C. [1 ]
Rivard, Eric [1 ]
Power, Philip P. [1 ]
机构：
[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 11期
关键词：
gallium; Group; 13; elements; insertion; low-valent species; MATRIX-ISOLATION; OXIDATIVE ADDITION; INFRARED-SPECTRA; AB-INITIO; GALLIUM; ACTIVATION; ALUMINUM; HYDRIDES; ATOMS; DERIVATIVES;
D O I：
10.1002/anie.200805982
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Mild-mannered: The low-valent aryl gallium(I) species :GaAr′ (Ar′ = 2,6-(2,6-iPr2C6H 3)2C6H3) undergoes addition to H2 or NH3 at room temperature and one atmosphere of pressure to afford 1 or 2 (see scheme), which were characterized by X-ray crystallography and NMR and IR spectroscopy. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码：2031 / 2034
页数：4
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