A Simple Method for Preparation of ZnO Nanoparticles as a Highly Efficient Nanocatalyst for N-Formylation of Primary and Secondary Amines under Solvent-Free Condition

被引：15

作者：

Alinezhad, Heshmatollah ^{[1
,2
]}

Salehian, Fatemeh ^{[1
]}

机构：

[1] Univ Mazandaran, Fac Chem, Babol Sar, Iran

[2] Univ Mazandaran, Nano & Biotechnol Res Grp, Babol Sar, Iran

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 05期

关键词：

amines; formic acid; N-formylation; solvent-free; ZnO nanoparticles; STEREOSELECTIVE-SYNTHESIS; FACILE METHOD; DERIVATIVES; ALCOHOLS; CATALYST; HYDROLYSIS; REDUCTION;

D O I：

10.1080/15533174.2012.741180

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A convenient reaction between alky, aryl, and heteroalkyl amines and formic acid as a formylating agent in the presence of catalytic amount of mechanochemically synthesized zinc oxide nanoparticles under solvent-free condition for the synthesis of corresponding N-formyl derivatives is described.

引用

页码：532 / 538

页数：7

共 50 条

[1] Guanidine derived ionic liquids: catalyst free medium for N-Formylation of amines [J].

Akbari, Jafar ;

Hekmati, Malak ;

Sheykhan, Mehdi ;

Heydari, Akbar .

ARKIVOC, 2009, :123-129

[2] SYNTHESIS OF BENZIMIDAZOLE DERIVATIVES USING HETEROGENEOUS ZnO NANOPARTICLES [J].

Alinezhad, Heshmatollah ;

Salehian, Fatemeh ;

Biparva, Pourya .

SYNTHETIC COMMUNICATIONS, 2012, 42 (01) :102-108

[3] The role of catalysis in the design, development, and implementation of green chemistry [J].

Anastas, PT ;

Bartlett, LB ;

Kirchhoff, MM ;

Williamson, TC .

CATALYSIS TODAY, 2000, 55 (1-2) :11-22

[4] FORMYLATION OF AMINES WITH CHLORAL AND REDUCTION OF THE N-FORMYL DERIVATIVES WITH LITHIUM ALUMINUM HYDRIDE [J].

BLICKE, FF ;

LU, CJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1952, 74 (15) :3933-3934

[5] Dication C(R1)-N(R2)2 synthons and their use in the synthesis of formamidines, amidines, and α-aminonitriles [J].

Cai, LS ;

Han, Y ;

Ren, SM ;

Huang, LF .

TETRAHEDRON, 2000, 56 (42) :8253-8262

[6] A new facile method for the synthesis of 1-arylimidazole-5-carboxylates [J].

Chen, BC ;

Bednarz, MS ;

Zhao, RL ;

Sundeen, JE ;

Chen, P ;

Shen, ZQ ;

Skoumbourdis, AP ;

Barrish, JC .

TETRAHEDRON LETTERS, 2000, 41 (29) :5453-5456

[7]

CHEN FMF, 1979, SYNTHESIS-STUTTGART, P709

[8] Metal hydride mediated reduction of 3-(alkylthio)oxindoles containing other potentially reducible groups [J].

Connolly, TJ ;

Durst, T .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1997, 75 (05) :536-541

[9]

Cullity B D., 1978, Elements of x-ray diffraction, V1

[10] A remarkably simple N-formylation of anilines using polyethylene glycol [J].

Das, Biswanath ;

Krishnaiah, Maddeboina ;

Balasubramanyam, P. ;

Veeranjaneyulu, Boyapati ;

Kumar, D. Nandan .

TETRAHEDRON LETTERS, 2008, 49 (14) :2225-2227

← 1 2 3 4 5 →