Hollow Metal-Organic Framework Microparticles Assembled via a Self-Templated Formation Mechanism

被引：58
作者：
Lee, Ilrang [1 ]
Choi, Sora [1 ]
Lee, Hee Jung [1 ]
Oh, Moonhyun [1 ]
机构：
[1] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
来源：
CRYSTAL GROWTH & DESIGN | 2015年 / 15卷 / 11期
关键词：
COORDINATION POLYMERS; DIRECTED FORMATION; DRUG-DELIVERY; MICROSPHERES; SITES; SHELL; SUPERSTRUCTURES; NANOPARTICLES; FABRICATION; PARTICLES;
D O I：
10.1021/acs.cgd.5b00919
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hollow particles are considered to be fascinating materials due to their useful applications and unique properties. Understanding the formation mechanism of hollow structures is critical for their controlled formation. Herein, we demonstrate the fabrication of hollow metal organic framework (hollow MOP) microparticles via a one-step solvothermal reaction of Zn(NO3)(2) and 1,3,5-benzenetricarboxylic acid (H3BTC) without extra template materials. The formation mechanism study of the hollow MOF reveals a unique self-templated formation mechanism consisting of three stages: (1) spherical microparticles are initially formed during the early stage of the reaction, (2) the initially formed spherical microparticles act as self-templates for the growth of new crystalline MOP materials during the middle stage of the reaction, and (3) the initially formed spherical microparticles spontaneously disappear for the formation of hollow MOFs during the late stage of the reaction.
引用
收藏
页码：5169 / 5173
页数：5
相关论文
共 47 条
[1]  
Ameloot R, 2011, NAT CHEM, V3, P382, DOI [10.1038/nchem.1026, 10.1038/NCHEM.1026]
[2]   Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites [J].
Bloch, Eric D. ;
Queen, Wendy L. ;
Krishna, Rajamani ;
Zadrozny, Joseph M. ;
Brown, Craig M. ;
Long, Jeffrey R. .
SCIENCE, 2012, 335 (6076) :1606-1610
[3]   Rational Design of Porous Coordination Polymers Based on Bis(phosphine)MCl2 Complexes That Exhibit High-Temperature H2 Sorption and Chemical Reactivity [J].
Bohnsack, Alisha M. ;
Ibarra, Ilich A. ;
Bakhmutov, Vladimir I. ;
Lynch, Vincent M. ;
Humphrey, Simon M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (43) :16038-16041
[4]   Metal-Organic Frameworks: From Molecules/Metal Ions to Crystals to Superstructures [J].
Carne-Sanchez, Arnau ;
Imaz, Inhar ;
Stylianou, Kyriakos C. ;
Maspoch, Daniel .
CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (18) :5192-5201
[5]  
Carné-Sánchez A, 2013, NAT CHEM, V5, P203, DOI [10.1038/NCHEM.1569, 10.1038/nchem.1569]
[6]   ZnO Hollow-Sphere Nanofilm-Based High-Performance and Low-Cost Photodetector [J].
Chen, Min ;
Hu, Linfeng ;
Xu, Jiaxi ;
Liao, Meiyong ;
Wu, Limin ;
Fang, Xiaosheng .
SMALL, 2011, 7 (17) :2449-2453
[7]   Multi Ball-In-Ball Hybrid Metal Oxides [J].
Cho, Won ;
Lee, Yun Hee ;
Lee, Hee Jung ;
Oh, Moonhyun .
ADVANCED MATERIALS, 2011, 23 (15) :1720-+
[8]   Nanoscale Metal-Organic Frameworks for Biomedical Imaging and Drug Delivery [J].
Della Rocca, Joseph ;
Liu, Demin ;
Lin, Wenbin .
ACCOUNTS OF CHEMICAL RESEARCH, 2011, 44 (10) :957-968
[9]   Two novel transition metal-organic frameworks based on 1,3,5-benzenetricarboxylate ligand: Syntheses, structures and thermal properties [J].
Fu, Ying ;
Li, Guobao ;
Liao, Fuhui ;
Xiong, Ming ;
Lin, Jianhua .
JOURNAL OF MOLECULAR STRUCTURE, 2011, 1004 (1-3) :252-256
[10]   Ultrahigh Porosity in Metal-Organic Frameworks [J].
Furukawa, Hiroyasu ;
Ko, Nakeun ;
Go, Yong Bok ;
Aratani, Naoki ;
Choi, Sang Beom ;
Choi, Eunwoo ;
Yazaydin, A. Oezguer ;
Snurr, Randall Q. ;
O'Keeffe, Michael ;
Kim, Jaheon ;
Yaghi, Omar M. .
SCIENCE, 2010, 329 (5990) :424-428
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