Synthesis of acrylic acid-based superabsorbent interpenetrated with sodium PVA sulfate using inverse-emulsion polymerization

被引:95
作者
Lim, DW
Song, KG
Yoon, KJ
Ko, SW [1 ]
机构
[1] Seoul Natl Univ, Dept Fiber & Polymer Sci, Seoul 151742, South Korea
[2] Chonbuk Natl Univ, Dept Text Engn, Chonju 561756, Chonbuk, South Korea
[3] Dankook Univ, Dept Text Engn, Seoul 140714, South Korea
关键词
acrylic acid; sodium PVA sulfate; interpenetrating; inverse-emulsion polymerization; superabsorbent;
D O I
10.1016/S0014-3057(01)00164-1
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Acrylic acid (AA)-based superabsorbent interpenetrated with sodium poly(vinyl alcohol) (PVA) sulfate (SPS) was prepared by inverse-emulsion polymerization. The disperse phase was prepared by dissolving AA and crosslinking monomer in aqueous SPS solution. Toluene was used as the continuous phase in which oil-soluble initiator and emulsifiers were dissolved. Sorbitan monooleate and ethyl cellulose were used as emulsifiers. The maximum water and saline absorbencies were 5041 and 211.4 g/g, respectively. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:579 / 586
页数:8
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