Simplifying Proton NMR Spectra by Instant Homonuclear Broadband Decoupling

被引:153
|
作者
Meyer, N. Helge [1 ]
Zangger, Klaus [1 ]
机构
[1] Karl Franzens Univ Graz, Inst Chem Organ & Bioorgan Chem, A-8010 Graz, Austria
基金
奥地利科学基金会;
关键词
homonuclear decoupling; NMR spectroscopy; pure shift; structure elucidation; TOCSY; SPECTROSCOPY; ELIMINATION; RESOLUTION; SIGNALS; BIRD;
D O I
10.1002/anie.201300129
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Shift work: The new NMR technique, instant homonuclear decoupling, which is achieved by slice-selective homo-decoupling during acquisition, yields pure-shift NMR spectra (see picture) which can be recorded like regular 1D spectra. No special data processing is necessary and this approach can also be easily adapted for the direct dimension of two- and multidimensional spectra, giving improved resolution. © 2013 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
引用
收藏
页码:7143 / 7146
页数:4
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