A supramolecularly templated catenane initiator and a controlled ring expansion strategy

被引:17
作者
Cao, Peng-Fei [1 ]
Bunha, Ajaykumar [1 ]
Mangadlao, Joey [1 ]
Felipe, Mary Jane [1 ]
Mongcopa, Katrina Irene [1 ]
Advincula, Rigoberto [1 ]
机构
[1] Case Western Reserve Univ, Dept Macromol Sci & Engn, Cleveland, OH 44106 USA
基金
美国国家科学基金会;
关键词
CLOSING METATHESIS; POLYMERIZATION; ROTAXANES; POLYMERS; INTERLOCKING; POLYSTYRENE; CYCLIZATION; STEP;
D O I
10.1039/c2cc35588d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the first synthesis of a catenated polymer via a ring-expansion strategy, which is based on a supramolecularly templated initiator. The high yielding synthesis and simple isolation method will enable the investigation and development of this unique polymer system for further applications.
引用
收藏
页码:12094 / 12096
页数:3
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