Copper-catalyzed one-pot synthesis of alkynylphophonates

被引：5

作者：

Song, Wang-Ze ^{[1
,2
]}

Li, Jun-Hao ^{[1
]}

Li, Ming ^{[1
]}

He, Jun-Nan ^{[3
]}

Dong, Kun ^{[1
]}

Ullah, Karim ^{[1
]}

Zheng, Yu-Bin ^{[3
]}

机构：

[1] Dalian Univ Technol, Sch Pharmaceut Sci & Technol, State Key Lab Fine Chem, 2 Linggong Rd, Dalian 116024, Peoples R China

[2] Zhongli Sci & Technol Grp Co Ltd, Changshu, Jiangsu, Peoples R China

[3] Dalian Univ Technol, Sch Chem Engn, Dalian, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2019年 / 49卷 / 05期

基金：

中国国家自然科学基金;

关键词：

Alkynylphophonates; copper; haloalkynes; one-pot; TERMINAL ALKYNES; H-PHOSPHONATES; ALKYNYLPHOSPHONATES; ACTIVATION;

D O I：

10.1080/00397911.2019.1566474

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Copper is found to be an effective catalyst for the preparation of alkynylphophonates. A novel copper-catalyzed one-pot synthesis of alkynylphophonates from terminal alkynes and dialkyl phosphites is developed which involves the haloalkynes intermediates. This method provides a unique and alternative approach to the well-documented oxidative coupling or arylpropiolic acid strategies. [GRAPHICS] .

引用

页码：697 / 703

页数：7

共 50 条

[1] Copper-Catalyzed One-Pot Synthesis of Thiazolidin-2-imines
Zorba, Leandros P.
Stylianakis, Ioannis
Tsoureas, Nikolaos
Kolocouris, Antonios
Vougioukalakis, Georgios C.
JOURNAL OF ORGANIC CHEMISTRY, 2024, 89 (11) : 7727 - 7740
[2] Copper-Catalyzed Domino One-Pot Synthesis of 2-(Arylselanyl) arylcyanamides
Ramana, Tamminana
Punniyamurthy, Tharmalingam
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2011, 2011 (25) : 4756 - 4759
[3] One-pot synthesis of polyfunctionalized quinolines via a copper-catalyzed tandem cyclization
Chen, Dianpeng
Sun, Xuejun
Shan, Yingying
You, Jinmao
ORGANIC & BIOMOLECULAR CHEMISTRY, 2018, 16 (41) : 7657 - 7662
[4] One-Pot Synthesis of Benzene and Pyridine Derivatives via Copper-Catalyzed Coupling Reactions
Han, Jianwei
Guo, Xin
Liu, Yafeng
Fu, Yajie
Yan, Rulong
Chen, Baohua
ADVANCED SYNTHESIS & CATALYSIS, 2017, 359 (15) : 2676 - 2681
[5] Electrophile-driven copper-catalyzed one-pot synthesis of 3-halogen quinoline derivatives
Cheng, Jie
Zhai, Hong
Bai, Jun
Tang, Jun
Lv, Ling
Sun, Bei
TETRAHEDRON LETTERS, 2014, 55 (30) : 4044 - 4046
[6] Copper-Catalyzed One-Pot Multicomponent Reactions: Synthesis of 4-Arylsulfenyl Pyrazoles
Oliveira, Daniela H.
Alves, Diego
Jacob, Raquel G.
Xavier, Maurcio C. D. F.
CURRENT ORGANIC SYNTHESIS, 2015, 12 (06) : 822 - 829
[7] Copper-catalyzed one-pot oxidative amidation between methylarenes and amines
Yang, Yuhang
Gu, Jiajia
Fang, Zheng
Yang, Zhao
Wei, Ping
Guo, Kai
RSC ADVANCES, 2017, 7 (37) : 22797 - 22801
[8] A simple copper-catalyzed two-step one-pot synthesis of indolo[1,2-a]quinazoline
Li, Chunpu
Zhang, Lei
Shu, Shuangjie
Liu, Hong
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2014, 10 : 2441 - 2447
[9] Copper-Catalyzed One-Pot Cascade Cyclization for the Synthesis of Isoindolo[2,1-a]quinoxalines
Li, Ling
Liu, Zhen-Ting
Hu, Xiang-Ping
ADVANCED SYNTHESIS & CATALYSIS, 2021, 363 (17) : 4272 - 4276
[10] Copper-Catalyzed One-Pot Synthesis of Dibenzofurans, Xanthenes, and Xanthones from Cyclic Diphenyl Iodoniums
Zhu, Daqian
Li, Min
Wu, Zhouming
Du, Yongliang
Luo, Bingling
Huang, Peng
Wen, Shijun
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2019, 2019 (28) : 4566 - 4571

← 1 2 3 4 5 →