Manganese-Catalyzed Cross-Coupling Reaction between Aryl Grignard Reagents and Alkenyl Halides

被引：49

作者：

Cahiez, Gerard ^{[1
]}

Gager, Olivier ^{[1
]}

Lecomte, Fabien ^{[1
]}

机构：

[1] Univ Paris 13, Dept Chem, CNRS, F-93017 Bobigny, France

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 22期

关键词：

D O I：

10.1021/ol802273e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aryl Grignard reagents react stereospecifically with alkenyl halides in the presence of manganese chloride (10%) to afford good yields of cross-coupling products.

引用

页码：5255 / 5256

页数：2

共 28 条

[1]

Alami M, 1998, SYNLETT, P325

[2]

[Anonymous], 2008, CHEM ORGANOMAGNESIUM

[3] Iron(III) salen-type catalysts for the cross-coupling of aryl Grignards with alkyl halides bearing β-hydrogens [J].

Bedford, RB ;

Bruce, DW ;

Frost, RM ;

Goodby, JW ;

Hird, M .

CHEMICAL COMMUNICATIONS, 2004, (24) :2822-2823

[4] Simple iron-amine catalysts for the cross-coupling of aryl Grignards with alkyl halides bearing β-hydrogens [J].

Bedford, RB ;

Bruce, DW ;

Frost, RM ;

Hird, M .

CHEMICAL COMMUNICATIONS, 2005, (33) :4161-4163

[5] MANGANESE(II) CATALYSIS .1. COUPLING REACTION OF IODOALKENES TO DIENES BY ORGANOLITHIUM REAGENTS IN PRESENCE OF MANGANESE(II) [J].

CAHIEZ, G ;

BERNARD, D ;

NORMANT, JF .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 113 (02) :99-106

[6] Unexpected cross-coupling reaction between o-chloroaryl ketones and organomanganese reagents [J].

Cahiez, G ;

Luart, D ;

Lecomte, F .

ORGANIC LETTERS, 2004, 6 (24) :4395-4398

[7] Iron-catalyzed homo-coupling of simple and functionalized arylmagnesium reagents [J].

Cahiez, G ;

Chaboche, C ;

Mahuteau-Betzer, F ;

Ahr, M .

ORGANIC LETTERS, 2005, 7 (10) :1943-1946

[8]

Cahiez G, 1998, SYNTHESIS-STUTTGART, P1199

[9]

Cahiez G, 1999, SYNTHESIS-STUTTGART, P2138

[10] Cu-catalyzed alkylation and Fe-catalyzed alkenylation of organomanganese reagents [J].

Cahiez, G ;

Marquais, S .

PURE AND APPLIED CHEMISTRY, 1996, 68 (01) :53-60

← 1 2 3 →