Hydroxyapatite-supported palladium (0) as a highly efficient catalyst for the Suzuki coupling and aerobic oxidation of benzyl alcohols in water

被引：94
作者：
Jamwal, Navjot [1 ]
Gupta, Monika [1 ]
Paul, Satya [1 ]
机构：
[1] Univ Jammu, Dept Chem, Jammu 180006, India
来源：
GREEN CHEMISTRY | 2008年 / 10卷 / 09期
关键词：
D O I：
10.1039/b802135j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A hydroxyapatite-supported palladium (0) catalyst was prepared and employed for the Suzuki coupling and aerobic oxidation of benzyl alcohols in water. This green procedure provides biaryls, heteroaryls and polyaryls in excellent yields with very high turnover numbers. The catalyst was equally efficient for the selective aerobic oxidation of benzyl alcohols under an air atmosphere. In both the cases, the catalyst can be recycled up to five times without significant loss of activity.
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页码：999 / 1003
页数：5
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