Polymerization of low molecular weight hydrogelators to form electrochromic polymers

被引：21
|
作者：
Kubiak, Peter S. [1 ]
Awhida, Salmah [2 ]
Hotchen, Christopher [1 ]
Deng, Wentao [1 ]
Alston, Ben [2 ]
McDonald, Tom O. [2 ]
Adams, Dave J. [2 ]
Cameron, Petra J. [1 ]
机构：
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
[2] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 52期
基金：
英国工程与自然科学研究理事会;
关键词：
ELECTROSYNTHESIS; NANOSTRUCTURES; GELATORS; SURFACE; GELS;
D O I：
10.1039/c5cc03053f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We present a method for the polymerization of low molecular weight hydrogelators to form polymers with unique structures. Carbazole-protected amino acids are shown to form hydrogels by self-assembly into fibrous structures. We show that is possible to directly electropolymerize the hydrogels. This results in the formation of microporous electrochromic polymers with distinctive structure. Polymers formed from the same gelator without the pregelation step show more compact structures. This method opens the possibility of creating polymers templated from pre-assembled gels that have the potential to be used in a wide range of applications.
引用
收藏
页码：10427 / 10430
页数：4
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