Excess molar volume of 2,2′-oxybis[propane] with benzene, toluene, cyclohexane, and methyl ethanoate at 298.15 K

被引:8
|
作者
Wisniak, J [1 ]
Infante, R
Peralta, RD
Ramos, LF
机构
[1] Ben Gurion Univ Negev, Dept Chem Engn, IL-84105 Beer Sheva, Israel
[2] Ctr Invest Quim Aplicada, Saltillo 25000, Coahuila, Mexico
关键词
excess thermodynamic properties; liquid mixtures;
D O I
10.1080/00319100108030682
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Densities of the binary systems 2,2'-oxybis [propane] with benzene, toluene, cyclohexane, and methyl ethanoate have been measured as a function of the composition, at 298.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densitometer. The calculated excess volumes were correlated with the Redlich-Kister equation and with Legendre's polynomials. The excess volumes are negative for the systems of 2,2'oxybis[propane] with benzene and toluene and positive with cyclohexane and methyl ethanoate.
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收藏
页码:625 / 636
页数:12
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