Calix[4]resorcinarene-based [Co16] coordination cages mediated by isomorphous auxiliary ligands for enhanced proton conduction

被引：36

作者：

Guo, Ting-Ting ^{[1
]}

Cheng, Dong-Ming ^{[1
]}

Yang, Jin ^{[1
]}

Xu, Xianxiu ^{[2
]}

Ma, Jian-Fang ^{[1
]}

机构：

[1] Northeast Normal Univ, Key Lab Polyoxometalate Sci, Dept Chem, Changchun 130024, Jilin, Peoples R China

[2] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Mol & Nano Probes, Minist Educ, Jinan 250014, Shandong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 44期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORK; SULFONIC-ACID GROUPS; SUPERPROTONIC CONDUCTIVITY; FUEL-CELLS; WATER; POLYMERS; CATALYST; SORPTION; CAPSULES; EXCHANGE;

D O I：

10.1039/c9cc01828j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We herein propose a design assembly of calix[4] resorcinarene-based proton-conductive [Co-16] coordination cages (1-SO3H and 1-OH) by carefully mediating the acidic sites of isomorphous auxiliary ligands. Markedly, 1-SO3H exhibits a proton conductivity that increased about 1 order of magnitude relative to its counterpart 1-OH, reaching 1.35 X 10(-2) S cm(-1) at 90 degrees C and under 98% relative humidity.

引用

页码：6277 / 6280

页数：4

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