A simple synthetic route to the formation of tetracopper(I) 2-mercaptothiazoline compounds -: The crystal structures of [Cu4(S-thiaz)4(PEt2Ph)2], [Cu4(S-thiaz)4(PEt3)2], [Cu4(S-thiaz)4]2, and [Cu4(S-thiaz)4]4

被引：1

作者：

Fuhr, O

Fernandez-Recio, L

Fenske, D

机构：

[1] Forschungszentrum Karlsruhe, Inst Nanotechnol, D-76021 Karlsruhe, Germany

[2] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 2006年 / 84卷 / 02期

关键词：

copper; 2-mercaptothiazoline; single crystal X-ray analysis;

D O I：

10.1139/V06-003

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of copper(I) acetate with 2-mercaptothiazoline (HS-thiaz) in the presence of tertiary phosphines lead to the formation of tetranuclear sulphur-bridged copper complexes. Depending on the reaction conditions, isolated clusters ([Cu-4(S-thiaz)(4)(PR3)(2)] (PR3 = PPh3 (1), PEt2Ph (2), PEt3 (3)), oligomeric compounds ([Cu-4(S-thiaz)(4)](2) (4) and [Cu-4(S-thiaz)(4)](4) (5)), or a one-dimensional polymer ([Cu-4(S-thiaz)(4)] (6)) are formed. The structures of the compounds 2-5 have been determined by single crystal X-ray analysis.

引用

页码：251 / 256

页数：6

共 19 条

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