Recent Insights into Manganese Oxides in Catalyzing Oxygen Reduction Kinetics

被引：379

作者：

Stoerzinger, Kelsey A. ^{[1
]}

Risch, Marcel ^{[2
]}

Han, Binghong ^{[1
]}

Shao-Horn, Yang ^{[1
,2
,3
]}

机构：

[1] MIT, Dept Mat Sci & Engn, Cambridge, MA 02139 USA

[2] MIT, Elect Res Lab, Cambridge, MA 02139 USA

[3] MIT, Dept Mech Engn, Cambridge, MA 02139 USA

来源：

ACS CATALYSIS | 2015年 / 5卷 / 10期

基金：

美国国家科学基金会;

关键词：

manganese oxide; electrocatalysis; oxygen reduction reaction; alkaline; valence; peroxide disproportionation; HYDROGEN-PEROXIDE DECOMPOSITION; METAL-AIR BATTERIES; RING-DISK ELECTRODE; ENHANCED ELECTROCATALYTIC ACTIVITY; ELECTROCHEMICAL WATER OXIDATION; RAY-ABSORPTION SPECTROSCOPY; PROTON-EXCHANGE MEMBRANE; JAHN-TELLER DISTORTION; PEROVSKITE-TYPE OXIDES; ALKALINE MEDIA;

D O I：

10.1021/acscatal.5b01444

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The sluggish kinetics of the oxygen reduction reaction (ORR) limit the efficiency of numerous oxygen-based energy conversion devices such as fuel cells and metal-air batteries. Among earth abundant catalysts, manganese-based oxides have the highest activities approaching that of precious metals. In this Review, we summarize and analyze literature findings to highlight key parameters that influence the catalysis of the ORR on manganese-based oxides, including the number of electrons transferred as well as specific and mass activities. These insights can help develop design guides for highly active ORR catalysts and shape future fundamental research to gain new knowledge regarding the molecular mechanism of ORR catalysis.

引用

页码：6021 / 6031

页数：11

共 126 条

[41] Tuning the Electrocatalytic Activity of Perovskites through Active Site Variation and Support Interactions
Hardin, William G.
Mefford, J. Tyler
Slanac, Daniel A.
Patel, Bijal B.
Wang, Xiqing
Dai, Sheng
Zhao, Xin
Ruoff, Rodney S.
Johnston, Keith P.
Stevenson, Keith J.
[J]. CHEMISTRY OF MATERIALS, 2014, 26 (11) : 3368 - 3376
[42] Oxygen atoms and molecules at La1-xSrxMnO3 surfaces
Harrison, Walter A.
[J]. PHYSICAL REVIEW B, 2010, 81 (04):
[43] Hayashi M, 1998, ELECTROCHEM SOLID ST, V1, P268
[44] Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
Hong, Wesley T.
Risch, Marcel
Stoerzinger, Kelsey A.
Grimaud, Alexis
Suntivich, Jin
Shao-Horn, Yang
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (05) : 1404 - 1427
[45] Catalytic activities of rare-earth manganites for cathodic reduction of oxygen in alkaline solution
Hyodo, T
Hayashi, M
Miura, N
Yamazoe, N
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (11) : L266 - L267
[46] Recent advances in non-precious metal catalysis for oxygen-reduction reaction in polymer electrolyte fuel cells
Jaouen, Frederic
Proietti, Eric
Lefevre, Michel
Chenitz, Regis
Dodelet, Jean-Pol
Wu, Gang
Chung, Hoon Taek
Johnston, Christina Marie
Zelenay, Piotr
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (01) : 114 - 130
[47] Preparation and electrochemical properties of urchin-like La0.8Sr0.2MnO3 perovskite oxide as a bifunctional catalyst for oxygen reduction and oxygen evolution reaction
Jin, Chao
Cao, Xuecheng
Zhang, Liya
Zhang, Cong
Yang, Ruizhi
[J]. JOURNAL OF POWER SOURCES, 2013, 241 : 225 - 230
[48] STUDIES ON MNO2 .2. RELATIONSHIP BETWEEN PHYSICOCHEMICAL PROPERTIES AND ELECTROCHEMICAL ACTIVITY OF SOME SYNTHETIC MNO2 OF DIFFERENT CRYSTALLOGRAPHIC FORMS
KANUNGO, SB
PARIDA, KM
SANT, BR
[J]. ELECTROCHIMICA ACTA, 1981, 26 (08) : 1147 - 1156
[49] Study of Jahn-Teller phase transitions in nonstoichiometric RMnO(3+x) orthomanganites (R=La,Nd,Sm,Eu)
Kasper, NV
Troyanchuk, IO
[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1996, 57 (11) : 1601 - 1607
[50] Hydrogen bonding and Jahn-Teller distortion in groutite, α-MnOOH, and manganite, γ-MnOOH, and their relations to the manganese dioxides ramsdellite and pyrolusite
Kohler, T
Armbruster, T
Libowitzky, E
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1997, 133 (02) : 486 - 500

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