Synthesis of Three Stereoisomers of p-tert-Butylthiacalix[4] arene Substituted with (Ethoxycarbonyl) methoxy and Fluorescent 1-Amidoanthraquinone Fragments

被引：10
作者：
Vavilova, Alena A. [1 ]
Nosov, Roman V. [1 ]
Mostovaya, Olga A. [1 ]
Stoikov, Ivan I. [1 ]
机构：
[1] Kazan Fed Univ, AM Butlerov Chem Inst, Kazan 420008, Russia
来源：
MACROHETEROCYCLES | 2016年 / 9卷 / 03期
基金：
俄罗斯科学基金会;
关键词：
Thiacalix[4] arene; synthesis; template effect; fluorescence spectroscopy; P-TERT-BUTYL; LOWER RIM; DERIVATIVES; THIACALIXARENES; BINDING;
D O I：
10.6060/mhc160531s
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New tetrasubstituted at the lower rim thiacalix[4]arenes containing both (ethoxycarbonyl) methoxy and 1-amidoanthraquinone fragments in three conformations: cone, partial cone and 1,3-alternate were synthesized. It was shown that depending on the alkali metal cation (sodium, potassium or cesium) in the alkylation of the diester based on p-tert-butylthiacalix[4] arene by 2-bromo-N-(9', 10'-dioxo-9', 10'-dihydroanthracene-1'-yl) acetamide template effect of metal cation was observed. The fluorescent properties of the obtained compounds were studied.
引用
收藏
页码：294 / 300
页数：7
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