Accessing functionalized porous aromatic frameworks (PAFs) through a de novo approach

被引:78
作者
Garibay, Sergio J. [1 ,2 ]
Weston, Mitchell H. [1 ,2 ]
Mondloch, Joseph E. [1 ,2 ]
Colon, Yamil J. [3 ]
Farha, Omar K. [1 ,2 ]
Hupp, Joseph T. [1 ,2 ]
Nguyen, SonBinh T. [1 ,2 ]
机构
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[2] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA
[3] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA
关键词
CARBON-DIOXIDE CAPTURE; POLYMER NETWORKS;
D O I
10.1039/c2ce26595h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Methyl-, hydroxymethyl-, and phthalimidomethyl-functionalized versions of the porous organic polymer PAF-1 have been obtained through de novo synthesis. The CO2 adsorption capacity of PAF-1-CH2NH2, obtained through the post-synthesis deprotection of PAF-1-CH2-phthalimide, has been shown to exceed that of PAF-1.
引用
收藏
页码:1515 / 1519
页数:5
相关论文
共 24 条
[1]   Porous aromatic frameworks: Synthesis, structure and functions [J].
Ben, Teng ;
Qiu, Shilun .
CRYSTENGCOMM, 2013, 15 (01) :17-26
[2]   Gas storage in porous aromatic frameworks (PAFs) [J].
Ben, Teng ;
Pei, Cuiying ;
Zhang, Daliang ;
Xu, Jun ;
Deng, Feng ;
Jing, Xiaofei ;
Qiu, Shilun .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (10) :3991-3999
[3]   Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area [J].
Ben, Teng ;
Ren, Hao ;
Ma, Shengqian ;
Cao, Dapeng ;
Lan, Jianhui ;
Jing, Xiaofei ;
Wang, Wenchuan ;
Xu, Jun ;
Deng, Feng ;
Simmons, Jason M. ;
Qiu, Shilun ;
Zhu, Guangshan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (50) :9457-9460
[4]   Nanoporous organic polymer networks [J].
Dawson, Robert ;
Cooper, Andrew I. ;
Adams, Dave J. .
PROGRESS IN POLYMER SCIENCE, 2012, 37 (04) :530-563
[5]   Designed synthesis of 3D covalent organic frameworks [J].
El-Kaderi, Hani M. ;
Hunt, Joseph R. ;
Mendoza-Cortes, Jose L. ;
Cote, Adrien P. ;
Taylor, Robert E. ;
O'Keeffe, Michael ;
Yaghi, Omar M. .
SCIENCE, 2007, 316 (5822) :268-272
[6]   Metal-Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit? [J].
Farha, Omar K. ;
Eryazici, Ibrahim ;
Jeong, Nak Cheon ;
Hauser, Brad G. ;
Wilmer, Christopher E. ;
Sarjeant, Amy A. ;
Snurr, Randall Q. ;
Nguyen, SonBinh T. ;
Yazaydin, A. Oezguer ;
Hupp, Joseph T. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (36) :15016-15021
[7]   Chemical reduction of a diimide based porous polymer for selective uptake of carbon dioxide versus methane [J].
Farha, Omar K. ;
Bae, Youn-Sang ;
Hauser, Brad G. ;
Spokoyny, Alexander M. ;
Snurr, Randall Q. ;
Mirkin, Chad A. ;
Hupp, Joseph T. .
CHEMICAL COMMUNICATIONS, 2010, 46 (07) :1056-1058
[8]   Synthesis, Properties, and Gas Separation Studies of a Robust Diimide-Based Microporous Organic Polymer [J].
Farha, Omar K. ;
Spokoyny, Alexander M. ;
Hauser, Brad G. ;
Bae, Youn-Sang ;
Brown, Samantha E. ;
Snurr, Randall Q. ;
Mirkin, Chad A. ;
Hupp, Joseph T. .
CHEMISTRY OF MATERIALS, 2009, 21 (14) :3033-3035
[9]   Covalent organic frameworks [J].
Feng, Xiao ;
Ding, Xuesong ;
Jiang, Donglin .
CHEMICAL SOCIETY REVIEWS, 2012, 41 (18) :6010-6022
[10]   Conjugated microporous poly (aryleneethynylene) networks [J].
Jiang, Jia-Xing ;
Su, Fabing ;
Trewin, Abbie ;
Wood, Colin D. ;
Campbell, Nell L. ;
Niu, Hongjun ;
Dickinson, Calum ;
Ganin, Alexey Y. ;
Rosseinsky, Matthew J. ;
Khimyak, Yaroslav Z. ;
Cooper, Andrew I. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (45) :8574-8578