Accessing functionalized porous aromatic frameworks (PAFs) through a de novo approach

被引：78

作者：

Garibay, Sergio J. ^{[1
,2
]}

Weston, Mitchell H. ^{[1
,2
]}

Mondloch, Joseph E. ^{[1
,2
]}

Colon, Yamil J. ^{[3
]}

Farha, Omar K. ^{[1
,2
]}

Hupp, Joseph T. ^{[1
,2
]}

Nguyen, SonBinh T. ^{[1
,2
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA

[3] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA

来源：

CRYSTENGCOMM | 2013年 / 15卷 / 08期

关键词：

CARBON-DIOXIDE CAPTURE; POLYMER NETWORKS;

D O I：

10.1039/c2ce26595h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Methyl-, hydroxymethyl-, and phthalimidomethyl-functionalized versions of the porous organic polymer PAF-1 have been obtained through de novo synthesis. The CO2 adsorption capacity of PAF-1-CH2NH2, obtained through the post-synthesis deprotection of PAF-1-CH2-phthalimide, has been shown to exceed that of PAF-1.

引用

页码：1515 / 1519

页数：5

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