Novel synthesis of phase-pure nano-particulate anatase and rutile TiO2 using TiCl4 aqueous solutions

被引：133

作者：

Yin, HB ^{[1
]}

Wada, Y ^{[1
]}

Kitamura, T ^{[1
]}

Sumida, T ^{[1
]}

Hasegawa, Y ^{[1
]}

Yanagida, S ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Suita, Osaka 5650871, Japan

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2002年 / 12卷 / 02期

关键词：

D O I：

10.1039/b105637a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Phase-pure anatase TiO2 nanocrystallites ranging from 2 to 10 nm in size were synthesized directly from a TiCl4 aqueous solution using citric acid as an additive. Citric acid was found to play a decisive role in stabilizing the TiCl4 aqueous solution, leading to the selective formation of the anatase TiO2 nanocrystallites in hydrothermal autoclaving. On the other hand, hydrothermal autoclaving of the rutile TiO2 embryos prepared by room-temperature peptization of the TiCl4 aqueous solution gave rod-like rutile TiO2 nanocrystallites (14-17 x 22-33 nm) under neutral conditions. The presence of KCl or NaCl enhanced the crystal growth of the rutile embryos in the hydrothermal process.

引用

页码：378 / 383

页数：6

共 19 条

[1] PHOTOCATALYTIC HYDROGENATION OF CH3CCH WITH H2O ON SMALL-PARTICLE TIO2 - SIZE QUANTIZATION EFFECTS AND REACTION INTERMEDIATES [J].