Transitions between paraelectric and ferroelectric phases of bent-core smectic liquid crystals in the bulk and in thin freely suspended films

被引:19
作者
Eremin, Alexey [1 ]
Floegel, Martin [1 ]
Kornek, Ulrike [1 ]
Stern, Stephan [1 ]
Stannarius, Ralf [1 ]
Nadasi, Hajnalka [2 ]
Weissflog, Wolfgang [2 ]
Zhu, Chenhui [3 ,4 ]
Shen, Yongqiang [3 ,4 ]
Park, Cheol Soo [3 ,4 ]
Maclennan, Joseph [3 ,4 ]
Clark, Noel [3 ,4 ]
机构
[1] Univ Magdeburg, Inst Expt Phys, ANP, D-39016 Magdeburg, Germany
[2] Univ Halle Wittenberg, Inst Phys Chem, D-06120 Halle, Saale, Germany
[3] Univ Colorado, Dept Phys, Boulder, CO 80309 USA
[4] Univ Colorado, Liquid Crystal Mat Res Ctr, Boulder, CO 80309 USA
来源
PHYSICAL REVIEW E | 2012年 / 86卷 / 05期
关键词
SUPERSTRUCTURAL CHIRALITY; POLAR ORDER; POLARIZATION; PATTERNS; FIELD;
D O I
10.1103/PhysRevE.86.051701
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We report on the contrasting phase behavior of a bent-core liquid crystal with a large opening angle between the mesogenic units in the bulk and in freely suspended films. Second-harmonic generation experiments and direct observation of director inversion walls in films in an applied electric field reveal that the nonpolar smectic C phase observed in bulk samples becomes a ferroelectric "banana" phase in films, showing that a mesogen with a small steric moment can give a phase with polar order in freely suspended films even when the corresponding bulk phase is paraelectric.
引用
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页数:10
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